On the origin of conductivity enhancement in polymer-ceramic composite electrolytes

Binod Kumar; Lawrence G.Scanlon; Robert J.Spry

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On the origin of conductivity enhancement in polymer-ceramic composite electrolytes

机译：高分子陶瓷复合电解质电导率增强的起源

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This paper analyzes thermal history dependent conductivity data of a PEO:LiBF_4-TiO_2 (20 wt./100) electrolyte to understand the origin of conductivity enhancement in polymer-ceramic composite electrolytes. The polymer-ceramic composite electrolytes are proposed to comprise of an assemblage of molecular dipoles whose orientations are dependent upon temperature, prior thermal history, and electric field.

机译：本文分析了PEO：LiBF_4-TiO_2（20 wt./100）电解质的热历史相关电导率数据，以了解聚合物-陶瓷复合电解质电导率增强的起因。提出了聚合物-陶瓷复合电解质，其包括分子偶极子的集合，其方向取决于温度，先前的热历史和电场。

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来源
《Journal of power sources》 |2001年第2期|p.337-342|共6页
作者
Binod Kumar; Lawrence G.Scanlon; Robert J.Spry;
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作者单位

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类能源与动力工程;
关键词
Compostite; Electrolyte; ionic conductivity; Dielectric constant;

机译：综合;电解质;离子电导率介电常数;

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1. Polymer-ceramic composite electrolytes for all-solid-state lithium batteries: Ionic conductivity and chemical interaction enhanced by oxygen vacancy in ceramic nanofibers [J] . Yang Hui, Abdullah Muhammad, Bright Joeseph, Journal of power sources . 2021,第MAYa31期

机译：全固态锂电池的聚合物 - 陶瓷复合电解质：在陶瓷纳米纤维中的氧空位增强离子电导率和化学相互作用
2. Dipoles and their possible effects on conductivity in polymer-ceramic composite electrolytes [J] . Binod Kumar, Stanley J. Rodrigues, Robert J. Spry Electrochimica Acta . 2002,第8期

机译：偶极子及其对高分子陶瓷复合电解质电导率的可能影响
3. Polymer-ceramic composite electrolytes: conductivity and thermal history effects [J] . Binod Kumar, Lawrence G. Scanlon Solid state ionics . 1999,第3a4期

机译：聚合物陶瓷复合电解质：电导率和热历史效应
4. Morphology Origin of Gradually Weakened Thermal-conductivity Enhancement for HDPE/MWCNTs Nanocomposites [C] . Xiao-Hong Yin, Can Yang, Shiju E, ASME international mechanical engineering congress and exposition . 2017

机译：HDPE / MWCNTs纳米复合材料逐渐减弱的导热性的形态学起源
5. Enhancement of ionic conductivity of solid and gel polymer electrolytes by nanoconfinement of electrolyte materials in alumina interpenetrating networks for room temperature lithium ion nanobattery applications. [D] . Jayasekara, Indumini U. 2016

机译：在室温互穿的锂离子纳米电池应用中，通过氧化铝互穿网络中电解质材料的纳米约束，可以提高固体和凝胶聚合物电解质的离子电导率。
6. Silica gel solid nanocomposite electrolytes with interfacial conductivity promotion exceeding the bulk Li-ion conductivity of the ionic liquid electrolyte filler [O] . Xubin Chen, Brecht Put, Akihiko Sagara, 2020

机译：界面导电性增强的硅胶固体纳米复合电解质离子液体电解质填充剂的整体锂离子电导率
7. Silica gel solid nanocomposite electrolytes with interfacial conductivity promotion exceeding the bulk Li-ion conductivity of the ionic liquid electrolyte filler [O] . Xubin Chen, Brecht Put, Akihiko Sagara, 2020

机译：硅胶固体纳米复合材料电解质具有界面电导率促进的电解质超过离子液体电解质填料的块状锂离子电导率
8. Methods of enhancing conductivity of a polymer-ceramic composite electrolyte [R] . 2003

机译：提高聚合物 - 陶瓷复合电解质的导电性的方法

On the origin of conductivity enhancement in polymer-ceramic composite electrolytes

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