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The preparation and performance of polyaniline coated polyester fabrics

机译:聚苯胺涂层聚酯织物的制备和性能

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摘要

In this experiment, the polyaniline coated fabrics were produced using aniline as the monomer by in-situ polymerization, p-toluenesulfonic acid as the doping agent and ammonium persulfate as the oxidant on the polyester fabric. The influence of different process conditions on the dielectric properties of the polyaniline coated fabric was explored. The fastness to rubbing of the coated fabrics was tested. The results show that the concentration of aniline and the oxidant both influence the dielectric properties of the fabrics. An appropriate aniline concentration is beneficial to increase the output of the polyaniline and reduce sudden and violent polymerization. A suitable oxidant concentration is beneficial to form polyaniline with a complete structure, reducing the occurrence of peroxide. When the aniline concentration was 0.4 mol/L and the oxidant concentration was 0.4 similar to 0.5 mol/L, the polarizing ability, loss ability and absorbing-attenuation ability of the fabrics to electromagnetic waves are all stronger. The dielectric properties of the obtained polyaniline coated fabrics varied corresponding to different types of dopants and doping levels. Compared to glacial acetic acid, hydrochloric acid and nitric acid, the dielectric properties of the prepared coated fabric were optimal when using p-toluenesulfonic acid as the dopant. When the concentration of the p-toluenesulfonic acid was 0.2 mol/L, the polarizing, loss and absorbing-attenuation abilities of the fabrics to electromagnetic waves are all stronger.
机译:在该实验中,通过原位聚合,作为单体,作为掺杂剂,作为掺杂剂和过硫酸铵作为聚酯织物上的氧化剂,使用苯胺作为单体制备聚苯胺涂层织物。探讨了不同工艺条件对聚苯胺涂层织物介电性质的影响。测试了涂层织物的耐摩擦的牢度。结果表明,苯胺和氧化剂的浓度均影响织物的介电性质。适当的苯胺浓度有利于增加聚苯胺的输出并减少突然和剧烈的聚合。合适的氧化剂浓度是有益的,具有完全结构的聚苯胺,减少过氧化物的发生。当苯胺浓度为0.4mol / L并且氧化剂浓度为0.4时,与0.5mol / L类似,织物与电磁波的偏振能力,损失能力和吸收 - 衰减能力均较强。所得聚苯胺涂覆织物的介电性质对应于不同类型的掺杂剂和掺杂水平。与冰醋酸,盐酸和硝酸相比,当使用对甲苯磺酸作为掺杂剂时,制备的涂覆织物的电介质性质是最佳的。当对甲苯磺酸的浓度为0.2mol / L时,织物与电磁波的偏振,损失和吸收 - 衰减能力均较强。

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  • 来源
    《The Journal of the Textile Institute》 |2021年第10期|1700-1707|共8页
  • 作者单位

    Tiangong Univ Sch Text Sci & Engn 399 Binshui West Rd Tianjin 300387 Peoples R China|Tianjin Polytech Univ Tianjin Key Lab Adv Text Composites Tianjin Peoples R China|Tianjin Municipal Key Lab Adv Fiber & Energy Stor Tianjin Peoples R China;

    Tiangong Univ Sch Text Sci & Engn 399 Binshui West Rd Tianjin 300387 Peoples R China;

    Tiangong Univ Sch Text Sci & Engn 399 Binshui West Rd Tianjin 300387 Peoples R China|Tianjin Polytech Univ Tianjin Key Lab Adv Text Composites Tianjin Peoples R China|Tianjin Municipal Key Lab Adv Fiber & Energy Stor Tianjin Peoples R China;

    Tiangong Univ Sch Text Sci & Engn 399 Binshui West Rd Tianjin 300387 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Preparation; performance research; polyaniline; coated fabric;

    机译:制备;性能研究;聚苯胺;涂层织物;

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