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首页> 外文期刊>Journal of Thermal Analysis and Calorimetry >Adsorption–desorption phenomena of water vapor on a superabsorbent polymer partially crosslinked with potassium
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Adsorption–desorption phenomena of water vapor on a superabsorbent polymer partially crosslinked with potassium

机译:水蒸气在与钾部分交联的高吸收性聚合物上的吸附-解吸现象

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摘要

The objective of this article is to study an amorphous superabsorbent polymer, which is able to absorb up to 300 times its weight of water. Adsorption–desorption phenomena of water vapor on the polymer as a function of temperature showed a reversibility of the adsorption–desorption phenomena. The thermal stability of the polymer at atmospheric pressure was also studied. The kinetic study of the desorption phenomena of water vapor on the polymer according to certain physicochemical parameters was discussed. The results showed that the kinetic regime governing the desorption phenomena of water vapor on the polymer is a process limited by a mono-dimensional diffusion for low masses and by a three-dimensional diffusion for high masses.
机译:本文的目的是研究一种无定形的超吸收性聚合物,它能够吸收高达其重量300倍的水。聚合物上水蒸气的吸附-解吸现象随温度的变化表现出吸附-解吸现象的可逆性。还研究了聚合物在大气压下的热稳定性。讨论了根据某些理化参数对水蒸气在聚合物上的解吸现象的动力学研究。结果表明,控制水蒸气在聚合物上解吸现象的动力学机制是受低质量的一维扩散和受高质量的三维扩散限制的过程。

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