Mesoporous Carbon/Zirconia Composites: A Potential Route to Chemically Functionalized Electrically-Conductive Mesoporous Materials

Jung-Min Oh; † Amar S. Kumbhar; ‡ Olt Geiculescu; † and Stephen E. Creager; †

首页> 外文期刊>Langmuir >Mesoporous Carbon/Zirconia Composites: A Potential Route to Chemically Functionalized Electrically-Conductive Mesoporous Materials

【24h】

Mesoporous Carbon/Zirconia Composites: A Potential Route to Chemically Functionalized Electrically-Conductive Mesoporous Materials

机译：介孔碳/氧化锆复合材料：化学功能化介电介孔材料的潜在途径

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Mesoporous nanocomposite materials in whichnnanoscale zirconia (ZrO2) particles are embedded in the carbonnskeleton of a templated mesoporous carbon matrix werenprepared, and the embedded zirconia sites were used tonaccomplish chemical functionalization of the interior surfaces ofnmesopores. These nanocomposite materials offer a uniquencombination of high porosity (e.g., ∼84% void space), electricalnconductivity, and surface tailorability. The ZrO2/carbon nanocompositesnwere characterized by thermogravimetric analysis,nnitrogen-adsorption porosimetry, helium pychnometry, powdernX-ray diffraction, Raman spectroscopy, scanning electronnmicroscopy, transmission electron microscopy, and X-ray photoelectronnspectroscopy. Comparison was made with templated mesoporous carbon samples prepared without addition of ZrO2.nTreatment of the nanocomposites with phenylphosphonic acid was undertaken and shown to result in robust binding of thenphosphonic acid to the surface of ZrO2 particles. Incorporation of nanoscale ZrO2 surfaces in the mesoporous compositenskeleton offers unique promise as a means for anchoring organophosphonates inside of pores through formation of robustncovalent Zr−O−P bonds.

机译：制备了介孔纳米复合材料，其中在模板化的介孔碳基体的碳骨架中嵌入了纳米级氧化锆（ZrO2）颗粒，并利用嵌入的氧化锆位点完成了纳米孔内表面的化学功能化。这些纳米复合材料提供了高孔隙率（例如约84％的空隙空间），导电性和表面可定制性的独特组合。通过热重分析，氮吸附孔隙率法，氦比重法，粉末X射线衍射，拉曼光谱，扫描电子显微镜，透射电子显微镜和X射线光电子能谱对ZrO2 /碳纳米复合材料进行了表征。与未添加ZrO2的模板化介孔碳样品进行了比较。n用苯基膦酸处理了纳米复合材料，结果表明，膦酸酯与ZrO2颗粒的表面牢固结合。在介孔复合骨架中掺入纳米级ZrO2表面提供了独特的前景，作为通过形成坚固的共价Zr-O-P键将有机膦酸酯固定在孔内的一种手段。

著录项

来源
《Langmuir》 |2012年第6期|3259-3270|共12页
作者
Jung-Min Oh; † Amar S. Kumbhar; ‡ Olt Geiculescu; † and Stephen E. Creager; †;
展开▼
作者单位

†Department of Chemistry Clemson University Clemson South Carolina 29634 United States‡Chapel Hill Analytical and Nanofabrication Laboratory University of North Carolina Chapel Hill North Carolina 27599 UnitedStates;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Ultrasensitive electrochemical immunosensor based on Au nanoparticles dotted carbon nanotube-graphene composite and functionalized mesoporous materials [J] . Lu J., Liu S., Ge S., Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices . 2012,第Null期

机译：基于金纳米粒子点碳纳米管-石墨烯复合材料和功能化介孔材料的超灵敏电化学免疫传感器
2. Studies on functionalized mesoporous materials: part 2. Characterization of sulphonated inorganic-organic composite materials based on mesoporous MCM-41 [J] . Karpov S. I., Roessner F., Selemenev V. F. Journal of porous materials . 2016,第2期

机译：功能化介孔材料的研究：第2部分。基于介孔MCM-41的磺化无机-有机复合材料的表征
3. Periodic mesoporous organosilica mesophases are versatile precursors for the direct preparation of mesoporous silica/carbon composites, carbon and silicon carbide materials [J] . Yang ZX, Xia YD, Mokaya R Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2006,第33期

机译：周期性的介孔有机硅中间相是用于直接制备介孔二氧化硅/碳复合材料，碳和碳化硅材料的通用前体
4. Design of Homogeneous Highly Ordered Functional Mesoporous Zirconia-silica Materials and Hierarchical Macro-mesoporous with the Highest Number of Active Sites from Single Precursors (sBuO)2-Al-O-Si-(OEt)3 ZrOSi(OtBu)34 [C] . International symposium on fine chemistry and functional polymers . 2008

机译：均匀高度有序功能介孔氧化锆 - 二氧化硅材料的设计和具有单个前体的最高数量的活性位点的分层宏观 - 中孔（SBUO）2-Al-O-Si-（OET）3和Zr OSI（OTBU）3 4
5. Preparation and functionalization of mesoporous silica, carbon and silica/carbon nanocomposites [D] . Hu, Qingyuan 2006

机译：介孔二氧化硅，碳和二氧化硅/碳纳米复合材料的制备和功能化
6. Effect of Surface and Bulk Properties of Mesoporous Carbons on the Electrochemical Behavior of GOx-Nanocomposites [O] . Tsai Garcia-Perez, Shouzhen Hu, Youngho Wee, 1970

机译：介孔碳的表面和体积性质对GOx-纳米复合材料电化学行为的影响
7. Novel synthetic routes of large-pore magnetic mesoporous nanocomposites (SBA-15/Fe3O4) as potential multifunctional theranostic nanodevices [O] . Z. Vargas-Osorio, M. A. González-Gómez, Y. Piñeiro, 2017

机译：大孔磁性介孔纳米复合材料（SBA-15 / FE3O4）的新型合成路线作为潜在的多功能Theranostic Nanodemices

Mesoporous Carbon/Zirconia Composites: A Potential Route to Chemically Functionalized Electrically-Conductive Mesoporous Materials

摘要

著录项

相似文献

相关主题

期刊订阅