Graft Copolymers for Blend Compatibilization: Mathematical Modeling of the Grafting Process

Ioana A. Gianoglio Pantano; Mariano Asteasuain; Claudia Sarmoria; Adriana Brandolin

首页> 外文期刊>Macromolecular reaction engineering >Graft Copolymers for Blend Compatibilization: Mathematical Modeling of the Grafting Process

【24h】

Graft Copolymers for Blend Compatibilization: Mathematical Modeling of the Grafting Process

机译：用于共混增容的接枝共聚物：接枝过程的数学模型

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The grafting of PE onto PS through a Friedel-Crafts reaction, which results in a mixture of PE-g-PS copolymer, unmodified PE, and modified PS, is investigated. The copolymer may be suitable for compatibilization of immiscible mixtures in the household plastic waste stream, where PE and PS are majority components. Since the compatibilization effect depends on the composition and block lengths in the copolymer, a model is presented for predicting the complete molecular weight distribution of the homopolymers and the chemical composition distribution of the graft copolymer. The model has potential for application in an optimization tool for the compatibilization process, as it is able to account for the opposing effects of competing reactions that characterize the graft reaction.

机译：研究了通过Friedel-Crafts反应将PE接枝到PS上，该反应导致PE-g-PS共聚物，未改性的PE和改性的PS的混合物。该共聚物可能适用于增容家用塑料废物流中的不溶混混合物，其中PE和PS是主要成分。由于增容效果取决于共聚物中的组成和嵌段长度，因此提出了一个模型，用于预测均聚物的完整分子量分布和接枝共聚物的化学组成分布。该模型具有潜力用于相容化工艺的优化工具中，因为它能够说明表征移植物反应的竞争性反应的相反作用。

著录项

来源
《Macromolecular reaction engineering》 |2012年第10期|p.406-418|共13页
作者
Ioana A. Gianoglio Pantano; Mariano Asteasuain; Claudia Sarmoria; Adriana Brandolin;
展开▼
作者单位

Planta Piloto de Ingenieria Ouimica (PLAPIOUI, UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca, Argentina;

Planta Piloto de Ingenieria Ouimica (PLAPIOUI, UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca, Argentina;

Planta Piloto de Ingenieria Ouimica (PLAPIOUI, UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca, Argentina;

Planta Piloto de Ingenieria Ouimica (PLAPIOUI, UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca, Argentina;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Grafting of Glycidyl Methacrylate onto Poly(lactide) and Properties of PLA/Starch Blends Compatibilized by the Grafted Copolymer [J] . Junshao Liu, Huihua Jiang, Liangbi Chen Journal of Polymers and the Environment . 2012,第3期

机译：甲基丙烯酸缩水甘油酯在聚丙交酯上的接枝以及与接枝共聚物相容的PLA /淀粉共混物的性能
2. Synthesis of silane-grafted ethylene vinyl acetate copolymer and its application to compatibilize the blend of ethylene-propylene-diene copolymer and silicone rubber [J] . Zhang Weijian, Yan Wei, Pan Renjie, Polymer engineering and science . 2018,第5期

机译：硅烷接枝乙烯乙酸乙烯酯共聚物的合成及其应用，以将乙烯 - 丙烯 - 二烯共聚物和硅橡胶混合物相容
3. Reactive Compatibilization: Formation of Double-Grafted Copolymers by In Situ Binary Grafting and Their Compatibilization Effect [J] . Chen Depei, Wang Hengti, Wo Yongjin ACS applied materials & interfaces . 2017,第38期

机译：反应性增容：通过原位二元接枝形成双嫁接共聚物及其相容作用
4. Graft Copolymers for Blend Compatibilization. Mathematical Modeling of the Grafting Process [C] . Ioana A. Gianoglio Pantano, Mariano Asteasuain, Claudia Sarmoria, AIChE annual meeting . 2010

机译：用于共混增容的接枝共聚物。接枝过程的数学建模
5. The functional monomers grafted polyolefins and their applications in the compatibilization of polymer blends. [D] . Yao, Li. 1996

机译：功能性单体接枝聚烯烃及其在聚合物共混物增容中的应用。
6. Biodegradable Blends of Grafted Dextrin with PLGA-block-PEG Copolymer as a Carrier for Controlled Release of Herbicides into Soil [O] . Kamila Lewicka, Piotr Rychter, Małgorzata Pastusiak, 2020

机译：接枝糊精与PLGA-嵌段-PEG共聚物的可生物降解共混物作为可控制地将除草剂释放到土壤中的载体
7. Dynamic mechanical analysis of binary and ternary polymer blends based on nylon copolymer/EPDM rubber and EPM grafted maleic anhydride compatibilizer [O] . 2007

机译：基于尼龙共聚物/ EpDm橡胶和Epm接枝马来酸酐增容剂的二元和三元聚合物共混物的动态力学分析

Graft Copolymers for Blend Compatibilization: Mathematical Modeling of the Grafting Process

摘要

著录项

相似文献

相关主题

期刊订阅