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首页> 外文期刊>Materials Chemistry and Physics >The effect of TiO_2 and ZrO_2 addition on the crystallization of Ce~(3+) doped yttrium aluminum garnet from glasses in the system Y_2O_3/Al_2O_3/SiO_2/AlF_3
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The effect of TiO_2 and ZrO_2 addition on the crystallization of Ce~(3+) doped yttrium aluminum garnet from glasses in the system Y_2O_3/Al_2O_3/SiO_2/AlF_3

机译:Y_2O_3 / Al_2O_3 / SiO_2 / AlF_3体系中添加TiO_2和ZrO_2对玻璃掺杂Ce〜(3+)钇铝石榴石结晶的影响

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摘要

The crystallization of yttrium aluminum garnet (YAG) doped with Ce~(3+) from alkali free glasses in the system Y_2O_3/Al_2O_3/SiO_2/AlF_3 has been investigated with and without the addition of ZrO_2 and/orTiO_2 as nucleation agents. X-ray diffraction (XRD), scanning electron microscopy (SEM) and differential thermal analysis (DTA) were used to characterize the crystallization process. Fluorescence microscopy and fluorescence spectroscopy were used to investigate optical properties. Thermal annealing of the glass was carried out at temperatures in the range from 1100 to 1400℃. In all samples studied, crystallization at temperatures >1300℃ lead to the formation of YAG as the main crystalline phase. If the glass contained TiO_2, the crystallization of YAG occurred at lower temperatures; here, already at 1150℃, YAG was the main crystalline phase. After annealing at 1300 ℃, the only crystalline phase formed was YAG. The fluorescence intensity showed a maximum at a wavelength of 532 nm and was largest in the sample solely doped with 5 mol% TiO_2. This proves that Ce~(3+) was incorporated into the YAG crystals.
机译:研究了在添加和不添加ZrO_2和/或TiO_2作为成核剂的情况下,在Y_2O_3 / Al_2O_3 / SiO_2 / AlF_3体系中从无碱玻璃中掺杂了Ce〜(3+)的钇铝石榴石(YAG)的结晶。 X射线衍射(XRD),扫描电子显微镜(SEM)和差热分析(​​DTA)用于表征结晶过程。荧光显微镜和荧光光谱用于研究光学性质。玻璃的热退火在1100至1400℃的温度范围内进行。在所有研究的样品中,在> 1300℃的温度下结晶都会导致形成YAG作为主要结晶相。如果玻璃中含有TiO_2,则YAG的结晶会在较低的温度下发生。在这里,在1150℃时,YAG是主要的结晶相。在1300℃退火后,形成的唯一结晶相是YAG。荧光强度在532 nm波长处显示最大值,并且在仅掺杂5 mol%TiO_2的样品中最大。这证明Ce〜(3+)被掺入了YAG晶体中。

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