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Dynamic mechanical, electrical, and actuation properties of ionic polymer metal composites using PVDF/PVP/PSSA blend membranes

机译:使用PVDF / PVP / PSSA共混膜的离子聚合物金属复合材料的动态机械,电气和驱动特性

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摘要

This paper reports the dynamic mechanical, electrical, and actuation properties of ionic polymer metal composite (IPMC) actuators that use polyvinylidene fluoride (PVDF)/polyvinyl pyrrolidone (PVP)/poly-styrene sulfonic acid (PSSA) blend membranes. In this research, two new IPMC actuators using PVDF/ PVP/PSSA blend membranes in the blend ratios of 60/15/25 and 40/30/30 were fabricated. All of the PVDF/PVP/PSSA-based IPMC actuator properties were compared with Nafion-based IPMC. The storage moduli of the IPMC using 60/15/25 blend membrane were higher than those of the IPMCs using the 40/ 30/30 blend membrane and the Nafion membrane. The current density of the IPMCs increased with increasing alternating current (AC) voltage and increasing frequencies. The current density of the Nafion-based IPMC was found to be higher than those of the PVDF/PVP/PSSA-based IPMCs. The actuation performances of the IPMCs were tested under direct current (DC) voltages of 1-3 V and AC voltages of 2-4 V. Under DC voltage, the PVDF/PVP/PSSA-based IPMC was actuated toward the anode side without back-relaxation, while the Nafion-based IPMC depicted back-relaxation. The blocking forces of all the IPMCs were evaluated as a function of time under DC voltages of 2 and 3 V. The tip displacements of the IPMCs increased with increasing AC voltages and decreased with increasing frequency. The bandwidth of the PVDF/PVP/PSSA-based IPMC was slightly higher than that of the Nafion-based IPMC.
机译:本文报告了使用聚偏二氟乙烯(PVDF)/聚乙烯吡咯烷酮(PVP)/聚苯乙烯磺酸(PSSA)混合膜的离子聚合物金属复合材料(IPMC)驱动器的动态机械,电气和驱动特性。在这项研究中,制造了两种使用PVDF / PVP / PSSA混合膜的新型IPMC执行器,其混合比为60/15/25和40/30/30。将所有基于PVDF / PVP / PSSA的IPMC执行器特性与基于Nafion的IPMC进行了比较。使用60/15/25共混膜的IPMC的储能模量高于使用40 / 30/30共混膜和Nafion膜的IPMC的储能模量。 IPMC的电流密度随着交流(AC)电压的增加和频率的增加而增加。发现基于Nafion的IPMC的电流密度高于基于PVDF / PVP / PSSA的IPMC的电流密度。在1-3 V的直流(DC)电压和2-4 V的交流电压下测试了IPMC的启动性能。在DC电压下,基于PVDF / PVP / PSSA的IPMC朝着阳极侧启动,没有反向松弛,而基于Nafion的IPMC则描述了反向松弛。在2和3 V的直流电压下,所有IPMC的阻塞力均作为时间的函数进行了评估。IPMC的尖端位移随交流电压的增加而增加,而随频率的增加而减小。基于PVDF / PVP / PSSA的IPMC的带宽略高于基于Nafion的IPMC的带宽。

著录项

  • 来源
    《Materials Chemistry and Physics》 |2012年第3期|928-937|共10页
  • 作者单位

    School of Mechanical Systems Engineering. Chonnam National University, Gwangju 500-757, Republic of Korea;

    School of Mechanical Systems Engineering. Chonnam National University, Gwangju 500-757, Republic of Korea;

    School of Mechanical Systems Engineering. Chonnam National University, Gwangju 500-757, Republic of Korea;

    School of Mechanical Systems Engineering. Chonnam National University, Gwangju 500-757, Republic of Korea;

    School of Mechanical Systems Engineering. Chonnam National University, Gwangju 500-757, Republic of Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    IPMC; storage modulus; current density; tip displacement; blocking force;

    机译:IPMC;储能模量当前密度;尖端位移阻挡力;

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