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Simultaneous synthesis of polyaniline nanofibers and metal (Ag and Pt) nanoparticles

机译:聚苯胺纳米纤维和金属(Ag和Pt)纳米粒子的同时合成

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摘要

An approach for the synthesis of Ag/Pt nanoparticle-incorporated polyaniline (PANI) nanofibers and Ag/Pt nanoparticles was developed that considers both thermodynamic and kinetic aspects. Ag/Pt nanoparticles and PANI nanofibers are generated simultaneously by the reduction of Ag~+Pt~(4+) ions to Ag/Pt nanoparticles and by the polymerization of aniline (ANI) to PANI nanofibers. The PANI nanofibers serve as anchor seeds for the formation of Ag/Pt nanoparticles. The simple and inexpensive route for the preparation of PANI-Ag/Pt nanocomposites can be extended to the polymerization of ANI derivatives and the formation of metal/metal oxides for applications such as sensors, direct methanol fuel cells, and capacitors.
机译:考虑到热力学和动力学方面,开发了一种合成Ag / Pt纳米粒子的聚苯胺(PANI)纳米纤维和Ag / Pt纳米粒子的合成方法。 Ag / Pt纳米纤维和PANI纳米纤维是通过将Ag〜+ Pt〜(4+)离子还原为Ag / Pt纳米颗粒并通过苯胺(ANI)聚合为PANI纳米纤维而同时生成的。 PANI纳米纤维可作为锚定种子,形成Ag / Pt纳米颗粒。制备PANI-Ag / Pt纳米复合材料的简单而廉价的方法可以扩展到ANI衍生物的聚合和金属/金属氧化物的形成,以用于传感器,直接甲醇燃料电池和电容器等应用。

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