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首页> 外文期刊>Materials Chemistry and Physics >Dielectric properties and diffuse phase transition in Ba_(1-x)Mg_xTi_(0.6)Zr_(0.4)O_3 solid solutions
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Dielectric properties and diffuse phase transition in Ba_(1-x)Mg_xTi_(0.6)Zr_(0.4)O_3 solid solutions

机译:Ba_(1-x)Mg_xTi_(0.6)Zr_(0.4)O_3固溶体的介电特性和扩散相变

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摘要

Perovskite types Ba_(1-x)Mg_xTi_(0.6)Zr_(0.4)O_3 (with x = 0.0, 0.07, 0.14) ceramics have been prepared through solid state reaction route. The room temperature XRD study suggests the compositions have single phase cubic symmetry. Microstructural studies have shown a step decrease in grain size. The dielectric study revels that the materials are of relaxor type and undergoes a diffuse type ferroelectric phase transition. The diffusivity increase with increase in Mg contents in the studied composition range. The transition temperature decreases with increase in Mg contents due to the decrease in grain size.
机译:通过固态反应路线制备了钙钛矿型Ba_(1-x)Mg_xTi_(0.6)Zr_(0.4)O_3(x = 0.0、0.07、0.14)陶瓷。室温XRD研究表明该组合物具有单相立方对称性。显微组织研究表明晶粒尺寸逐渐减小。介电研究表明材料是弛豫型的,并经历了扩散型铁电相变。在所研究的组成范围内,扩散率随着镁含量的增加而增加。由于晶粒尺寸的减小,转变温度随着Mg含量的增加而降低。

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