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首页> 外文期刊>Materials Chemistry and Physics >A single precursor pit for pitting corrosion on defect of tinplate alloy layer visualized by atomic force microscopy
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A single precursor pit for pitting corrosion on defect of tinplate alloy layer visualized by atomic force microscopy

机译:用原子力显微镜观察马口铁对马口铁合金层缺陷的腐蚀

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摘要

The gray points highly disperse on the alloy layer surface after free tin coating removed on poorly corrosion-resistant tinplate. The morphology and composition of normal area and the gray point were investigated by scanning electron microscopy (SEM), atomic force microscopy (AFM) and energy dispersion spectroscopy (EDS) on the same tinplate sheet. Additional, the cyclic voltammetry results indicate that corrosion resistance of alloy layer containing gray points is less than that of normal area. Those indicate that gray points are defects of Sn-Fe alloy layer. AFM was applied to obtain detail information on topography change of the gray point in electrolyte. Furthermore, profile lines of the sample at varied time were determined and delivered additional arguments for corrosion rate of the gray point. The results of a single pit corrosion measurement show that corrosion rate is determined by a mass-transport controlled mechanism in acid electrolyte.
机译:在耐蚀性较差的马口铁上除去自由的锡涂层后,灰点在合金层表面上高度分散。在同一马口铁板上通过扫描电子显微镜(SEM),原子力显微镜(AFM)和能量分散谱(EDS)研究了正常区域和灰点的形态,组成。另外,循环伏安法结果表明,含有灰点的合金层的耐蚀性小于正常面积。这些表明灰点是Sn-Fe合金层的缺陷。应用原子力显微镜获得有关电解质中灰点的形貌变化的详细信息。此外,确定了样品在不同时间的轮廓线,并提供了有关灰点腐蚀速率的其他参数。单坑腐蚀测量的结果表明,腐蚀速率是由质量控制的机制决定的。

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