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首页> 外文期刊>Materials and Manufacturing Processes >Rapid Synthesis of Phenyl-Functionalized Mesoporous Silica Using as a Highly Efficient Fiber Coating of Solid-Phase Microextraction
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Rapid Synthesis of Phenyl-Functionalized Mesoporous Silica Using as a Highly Efficient Fiber Coating of Solid-Phase Microextraction

机译：使用固相微萃取的高效纤维涂层快速合成苯基官能化介孔二氧化硅

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A rapid synthesis of highly ordered phenyl-functionalized MCM-41 (Phen-MCM-41-R) mesoporous silica was performed by using cetyltrimethylammonium bromide as the template and tetraethyl orthosilicate as the silica source under alkaline conditions within 3Â h. The samples were characterized by fourier transform infrared (FTIR) spectra, small-angle X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption-desorption, and thermogravimetric analysis (TGA). It has been found that the resultant material still preserves a desirable two-dimensional P6Â mm hexagonal structure and has large specific surface area, large pore volume, and good thermal stability. High extraction efficiency of dibutyl phthalate (DBP) is obtained using the phenyl-MCM-41-R as a fiber coating of solid-phase microextraction. Three hours for the self-assembly step is enough during the process of synthesis and has no unfavorable effect on the extraction behavior of phenyl-MCM-41-R as a mesoporous fiber coating.View full textDownload full textKeywordsExtraction efficiency, Fiber coating, Mesoporous silica, Phenyl-functionalized MCM-41, Rapid synthesis, Solid-phase microextractionRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/10426911003720730
机译：通过使用十六烷基三甲基溴化铵作为模板和原硅酸四乙酯作为二氧化硅源，在碱性条件下在3 h内快速合成高度有序的苯基官能化MCM-41（Phen-MCM-41-R）介孔二氧化硅。通过傅里叶变换红外光谱，小角X射线衍射，扫描电子显微镜，透射电子显微镜，N 2 吸附-脱附对样品进行表征。 ，以及热重分析（TGA）。已经发现，所得材料仍然保留了理想的二维P6mm六角形结构，并具有大的比表面积，大的孔体积和良好的热稳定性。使用苯基-MCM-41-R作为固相微萃取的纤维涂层，可以获得高萃取效率的邻苯二甲酸二丁酯（DBP）。合成过程中三个小时的自组装步骤就足够了，并且对苯基-MCM-41-R作为中孔纤维涂层的萃取行为没有不利影响。查看全文下载全文关键字萃取效率，纤维涂层，中孔二氧化硅，苯基功能化的MCM-41，快速合成，固相微萃取相关变量var addthis_config = {ui_cobrand：“泰勒和弗朗西斯在线”，servicescompact：“ citeulike，netvibes，twitter，technorati，delicious，linkedin，facebook，stumbleupon，digg，google ，more“，pubid：” ra-4dff56cd6bb1830b“};添加到候选列表链接永久链接http://dx.doi.org/10.1080/10426911003720730

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