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Photosynthesis of silver nanoparticles using Durio zibethinus aqueous extract and its application in catalytic reduction of nitroaromatics, degradation of hazardous dyes and selective colorimetric sensing of mercury ions

机译:Durio zibethinus水提取物光合作用制备银纳米颗粒及其在硝基芳族化合物催化还原,有害染料降解和汞离子选择性比色检测中的应用

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A simple green route was reported to prepare highly stable silver nanoparticles. The aqueous leaf extract of Durio zibethinus reduces Ag + to Ago in the presence of natural sunlight. The capping and stabilization of dAgNPs by the phytoconstituents of Durio zibethinus was confirmed by FTIR. TEM confirms that the dAgNPs are spherical in shape with a size range between 10-25 nm. XRD pattern confirmed that the dAgNPs are arranged in the face centred cubic structure. The catalytic activity of the dAgNPs was proved by sodium borohydride mediated reduction of nitro aromatic compounds and degradation hazardous organic dyes. The reaction kinetics was analysed by pseudo-first order equation. Regardless of the efficacy of degrading organic dyes, we showed by zebrafish mortality assay that the toxicity of the dye degraded water reduced drastically. Besides catalysis, the dAgNPs has the potential to selective calorimetric sensing of hazardous mercury ion in aqueous solution.
机译:据报道,一条简单的绿色路线可制备高度稳定的银纳米颗粒。在自然阳光下,Durio zibethinus的叶子提取物将Ag +还原为Ago。 FTIR证实了Durio zibethinus的植物成分对dAgNP的封端和稳定作用。 TEM证实dAgNPs为球形,大小范围在10-25 nm之间。 XRD图谱证实dAgNPs排列在面心立方结构中。硼氢化钠介导的硝基芳香族化合物的还原和有害有机染料的降解证明了dAgNPs的催化活性。通过拟一阶方程分析反应动力学。不管降解有机染料的功效如何,我们通过斑马鱼死亡率试验表明,染料降解的水的毒性急剧降低。除催化作用外,dAgNPs还具有选择性量热法检测水溶液中有害汞离子的潜力。

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