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Effect of tungsten concentration on microstructures of Co-10Ni-6Al-(0,2,4,6) W-6Ti (at%) cobalt-based superalloys

机译:钨浓度对Co-10Ni-6Al-(0,2,4,6)W-6Ti(at%)钴基高温合金显微组织的影响

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摘要

The effects of reducing the W concentration (and concomitantly mass density) of Co-10Ni-6Al-xW-6Ti at% Co-based superalloys, with a γ(f.c.c) plus γ'(L1_2) microstructure, is investigated for a series of alloys with W concentrations of 6 at% (baseline alloy), 4 and 2 at% (W-reduced) and 0 at% (W-free). The γ'(L1_2) solvus temperature decreases strongly (by 46 ℃ per 1 at% reduction in W), while the liquidus and solvus temperatures decrease mildly (3-5 ℃ per 1 at% W reduction) as measured by differential scanning calorimetry. Scanning electron microscopy was used to image phase formation in all alloys. When aging at 900 or 1000 ℃ for 256 h, the W reduction does not result in the appearance of additional phases within the grains beyond the γ(f.c.c) and γ'(L1_2) phases present in the original alloy. Grain-boundary precipitates are present for all alloy compositions: W-rich or W-free precipitates after aging at 1000 ℃, and coarsened γ'(L1_2) precipitates after aging at 900 ℃. The composition of grain boundary precipitates were measured with energy-dispersive X-ray spectroscopy. Vickers microhardness values decrease with decreasing W content, due to a reduction in γ'(L1_2) precipitation and reduced solid-solution strengthening.
机译:研究了一系列具有γ(fcc)和γ'(L1_2)微结构的Co%Ni基Co-10Ni-6Al-xW-6Ti的Co-10Ni-6Al-xW-6Ti的W浓度降低(以及随之而来的质量密度)的影响。 W浓度为6 at%(基线合金),4和2 at%(降低W)和0 at%(无W)的合金。用差示扫描量热法测得,γ'(L1_2)的固溶线温度急剧降低(每降低1 at%W降低46℃),而液相线和固溶线温度则缓慢降低(每降低1 at%W降低3-5℃)。使用扫描电子显微镜对所有合金中的相形成进行成像。当在900或1000℃时效256 h时效时,W的减少不会导致晶粒内出现超过原始合金中γ(f.c.c)和γ'(L1_2)相以外的其他相。所有合金成分均存在晶界沉淀:在1000℃时效后富W或无W沉淀,在900℃时效后较粗的γ'(L1_2)沉淀。晶界析出物的组成通过能量色散X射线光谱法测定。维氏显微硬度值随着W含量的降低而降低,这是由于γ'(L1_2)沉淀的减少和固溶强化的降低。

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  • 来源
    《Materials Science and Engineering》 |2017年第17期|481-486|共6页
  • 作者单位

    Department of Materials Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208-3108, USA;

    NASA Glenn Research Center, 21000 Brookpark Road, Cleveland, OH 44135, USA;

    Department of Materials Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208-3108, USA;

    NASA Glenn Research Center, 21000 Brookpark Road, Cleveland, OH 44135, USA;

    Department of Materials Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208-3108, USA,Northwestern University Center for Atom-Probe Tomography (NUCAPT), 2220 Campus Drive, Evanston, IL 60208-3108, USA,NanoAl LLC, Illinois Science + Technology Park, 8025 Lamon Ave, Suite 446, Skokie, IL 60077, USA;

    Department of Materials Science and Engineering, Northwestern University, 2220 Campus Drive, Evanston, IL 60208-3108, USA,NanoAl LLC, Illinois Science + Technology Park, 8025 Lamon Ave, Suite 446, Skokie, IL 60077, USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Cobalt alloys; Superalloy; Intermetallic; L1_2, grain boundary;

    机译:钴合金;高温合金金属间化合物L1_2;晶界;

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