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Phase equilibria of an Al_(0.5)CrFeCoNiCu High Entropy Alloy

机译:Al_(0.5)CrFeCoNiCu高熵合金的相平衡

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The phase equilibria of an Al_(0.5)CrFeCoNiCu High Entropy Alloy has been studied following 1000 h exposures at 700,850 and 1000 ℃. Above 1000 ℃, the material comprised of two fcc solid solutions, one a multi-element phase and the other a Cu rich phase. Below 1000 ℃, the fcc phases persisted, but were accompanied by the formation of two intermetallic compounds. In contrast to previous reports, the L1_2 phase was also found to precipitate through a solvus at ~ 850 ℃. The results indicated that a solid state single phase field does not exist in this material at any temperature and all of the observed phases could be rationalised with reference to existing phase diagrams. This suggests that configurational entropy does not overcome the enthalpic contribution to the Gibbs energy, which governs phase equilibria of this alloy.
机译:研究了Al_(0.5)CrFeCoNiCu高熵合金在700,850和1000℃暴露1000 h后的相平衡。在1000℃以上,该材料由两种fcc固溶体组成,一种为多元素相,另一种为富铜相。在1000℃以下,fcc相持续存在,但伴随有两种金属间化合物的形成。与以前的报道相反,在约850℃时还发现L1_2相通过固溶体沉淀。结果表明,该材料在任何温度下都不存在固态单相场,并且可以参照现有相图对所有观察到的相进行合理化处理。这表明构型熵不能克服焓对吉布斯能量的贡献,吉布斯能量决定了该合金的相平衡。

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