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Physico-chemical aspects of bonding in iron aluminides

机译:铝化铁中键合的物理化学方面

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摘要

Non-empirical study of the site preference occupation for Ni, Co, Mn, Cr, V and Ti substituting for Fe in Fe_(0.75)Al_(0.25) showed that the preference to occupy the γ sublattice decreases in the direction from Ti to Ni. For Cr alloying the change of concentrations from 1.25% to 5% leads to relocation of Cr atoms from a to γ sublattice. The interpretation of results is based on the ideas of the theory of chemical coordination bonds in transition metals.
机译:对Fe_(0.75)Al_(0.25)中的Fe替代Ni,Co,Mn,Cr,V和Ti的位点优先职业的非经验研究表明,占据γ子晶格的优先权在从Ti到Ni的方向上降低。对于铬合金,浓度从1.25%到5%的变化会导致Cr原子从α亚晶格迁移到γ亚晶格。结果的解释基于过渡金属中化学配位键理论的思想。

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