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Mercaptoacetic acid-functionalized reduced graphene Oxide for methylene blue removal

机译:巯基乙酸官能化的氧化石墨烯用于亚甲基蓝的去除

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摘要

Chlorine in chlorine-functionalized reduced graphene oxide (ClRGO) was substituted by the mercaptoacetic acid, and mercaptoacetic acid-functionalized reduced graphene oxide (MRGO) was formed. Some chlorine atoms in the central of sheet were eliminated, and then the sheet was sequentially reduced. The sulfur content of MRGO is obviously lower than the chlorine content of ClRGO. Although mercaptoacetic acid is bigger than the chlorine, the average interlayer space of MRGO is smaller than ClRGO. The average interlayer space of graphitic material should be influenced by pillaring agent. The crystallization degree of MRGO is higher than ClRGO. The carboxylic group provides the graphene sheet with extra efficiency to accommodate adsorbate by providing extra binding sites on sheet to hold methylene blue between graphene sheets. The adsorption capacity for methylene blue is 180.4 mg/g, which is higher than that (78.2 mg/g) of RGO.
机译:用巯基乙酸代替氯官能化的还原氧化石墨烯(ClRGO)中的氯,形成巯基乙酸官能化的还原氧化石墨烯(MRGO)。除去片材中央的一些氯原子,然后依次还原片材。 MRGO的硫含量明显低于ClRGO的氯含量。尽管巯基乙酸比氯大,但MRGO的平均层间空间小于ClRGO。石墨材料的平均层间空间应受支柱剂的影响。 MRGO的结晶度高于ClRGO。羧基通过在薄片上提供额外的结合位点以在石墨烯薄片之间保持亚甲基蓝,从而为石墨烯薄片提供了额外的效率来容纳被吸附物。亚甲基蓝的吸附量为180.4 mg / g,高于RGO的吸附量(78.2 mg / g)。

著录项

  • 来源
    《Materials Science and Engineering》 |2019年第6期|9-16|共8页
  • 作者单位

    Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China;

    Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China;

    Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China;

    Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China;

    Weinan High Technol High Sch, Weinan 714000, Shanxi, Peoples R China;

    Xinxiang Univ, Inst Energy & Fuel, Xinxiang 453003, Henan, Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Graphene; Graphene oxide; Adsorption; Methylene blue;

    机译:石墨烯;氧化石墨烯;吸附;亚甲基蓝;

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