...
首页> 外文期刊>Materials Science and Engineering >Synthesis, structural, magnetic and sodium deinsertion/insertion properties of a sodium ferrous metaphosphate, NaFe(PO_3)_3
【24h】

Synthesis, structural, magnetic and sodium deinsertion/insertion properties of a sodium ferrous metaphosphate, NaFe(PO_3)_3

机译:偏磷酸亚铁钠(NaFe(PO_3)_3)的合成,结构,磁性和钠去插入/插入特性

获取原文
获取原文并翻译 | 示例
           

摘要

A metaphosphate NaFe(PO_3)_3 compound has been obtained by solid state method here. This title compound belongs to the orthorhombic structure with the space group of P2_12_12_1 (No. 19) and lattice parameters of a = 14.3390(3)A, b = 14.3374(2)A, c= 14.3642(1) A. Its structure can be described as made up of infinite (PO_3)~1- chains connected by FeO_6 octahedra, while the monovalent Na cations are located in the tunnels determined by the connection of PO_4 tetrahedrons and FeO_6 octahedrons. Besides, the morphology, vibrational spectra, magnetic and sodium deinsertion/insertion properties of NaFe(PO_3)_3 compound are also presented and discussed here for the first time, which can provide more information about the physicochemical properties of this metaphosphate compound.
机译:在此,通过固态方法获得了偏磷酸盐NaFe(PO_3)_3化合物。该标题化合物属于正交结构,空间群为P2_12_12_1(第19号),晶格参数为a = 14.3390(3)A,b = 14.3374(2)A,c = 14.3642(1)A。其结构可以被描述为由通过FeO_6八面体连接的无限(PO_3)〜1-链组成,而单价Na阳离子位于由PO_4四面体和FeO_6八面体的连接确定的隧道中。此外,本文还首次介绍了NaFe(PO_3)_3化合物的形貌,振动光谱,磁性和钠去插入/插入性质,可以为该偏磷酸盐化合物的理化性质提供更多信息。

著录项

  • 来源
    《Materials Science and Engineering》 |2015年第7期|58-66|共9页
  • 作者单位

    School of Material Science and Engineering, South China University of Technology, Guangzhou 510640, PR China;

    State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, PR China,School of Physics, South China University of Technology, Guangzhou 510640, PR China;

    School of Physics, South China University of Technology, Guangzhou 510640, PR China;

    School of Physics, South China University of Technology, Guangzhou 510640, PR China;

    School of Material Science and Engineering, South China University of Technology, Guangzhou 510640, PR China;

    School of Material Science and Engineering, South China University of Technology, Guangzhou 510640, PR China;

    School of Material Science and Engineering, South China University of Technology, Guangzhou 510640, PR China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Sodium iron(Ⅱ) metaphosphate; Crystal structure; Vibrational spectra; Magnetic property; Sodium deinsertion/insertion properties;

    机译:偏磷酸铁钠晶体结构振动光谱磁性钠去插入/插入特性;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号