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首页> 外文期刊>Materials Science and Engineering >Effect Of Fe On The Structure And Magnetic Properties Of Sm-co-cu-fe-zr Melt-spun Ribbons
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Effect Of Fe On The Structure And Magnetic Properties Of Sm-co-cu-fe-zr Melt-spun Ribbons

机译:Fe对Sm-co-cu-fe-zr熔纺带结构和磁性的影响

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The Sm_(12)Co_(60-x)Cu_6Fe_(19+x)Zr_3 (x = 0-10) ribbons are prepared by melt-spun at 20m/s, and the effects of Fe content on structure and magnetic properties of the ribbons are studied. It is observed that all as-spun ribbons are composed of Sm(Co,M)_7 phase and small amount of α-Fe phase. Fe addition does not change phase composition of the ribbons. However, Fe can supersaturatedly dissolve in Sm(Co,M)_7 and constrain the amount of α-Fe in the melt-spun ribbons. 1:7H phase in the x = 3 ribbons starts to decompose when the ribbons are annealed above 800 ℃, that is, SmCo 1:7H→ SmCo 1:5H + SmCo 2:17R + α-Fe. α-Fe is shown as precipitated phase, and all these precipitated phases are distributed in the form of fine needles. Magnetization of all melt-spun ribbons is determined by nucleation field; And magnetization of the x = 3 ribbons annealed at different temperatures is determined by different coercivity mechanisms. In the maximum applied field of 20kOe, x= 1 ribbons annealed at 800 ℃ gets the highest coercivity of 2.262 kOe; x = 5 as-spun ribbons gets the highest remanence of 36.94 emu/g.
机译:Sm_(12)Co_(60-x)Cu_6Fe_(19 + x)Zr_3(x = 0-10)薄带是通过以20m / s熔纺的方法制备的,并且Fe含量对合金的结构和磁性能的影响丝带研究。可以看出,所有初生薄带均由Sm(Co,M)_7相和少量的α-Fe相组成。 Fe的添加不会改变带的相组成。但是,Fe可以过饱和地溶解在Sm(Co,M)_7中,并限制熔纺带中α-Fe的含量。当碳带在800℃以上退火时,x = 3碳带中的1:7H相开始分解,即SmCo 1:7H→SmCo 1:5H + SmCo 2:17R +α-Fe。 α-Fe显示为沉淀相,所有这些沉淀相均以细针状分布。所有熔纺带的磁化强度由成核场决定。通过不同的矫顽力机制确定在不同温度下退火的x = 3条带的磁化强度。在20kOe的最大外加磁场中,在800℃退火的x = 1条碳带的矫顽力最高,为2.262 kOe。 x = 5根纺出的色带具有36.94 emu / g的最高剩磁。

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