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Influence of oxygen adsorption and diffusion on the overlapping of intergranular potential barriers in SnO_2 thick films

机译:氧的吸附和扩散对SnO_2厚膜中晶间势垒重叠的影响

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摘要

Complex impedance analysis and transient response studies in SnO_2 thick films show the impedance dependence on gaseous environment and temperature. Possible mechanisms responsible for the found behaviors are proposed. The influence of temperature on the oxygen diffusion into the grains annihilating oxygen vacancies was detected. In particular, we found the transition from having bulk regions unaffected by surface phenomena to the overlapping of potential barriers due to an oxidizing gas.
机译:SnO_2厚膜的复杂阻抗分析和瞬态响应研究表明,阻抗与气体环境和温度有关。提出了可能对发现的行为负责的机制。检测到温度对氧扩散到消除氧空位的晶粒中的影响。特别地,我们发现了从具有不受表面现象影响的主体区域到由于氧化气体而导致的势垒重叠的过渡。

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