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Improved structural and magnetic properties of Polypyrrole substituted spinel ferrites composites

机译:改善聚吡咯取代尖晶石铁氧体复合材料的结构和磁性

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摘要

The spinel ferrites Mg0.96Pr0.04Fe2O4 were synthesized by co-precipitate route. The in-situ polymerization technique is employed to prepare Polypyrrole. In present work, nanocomposites were manufactured by intermixing of Polypyrrole polymers and Mg-Pr-ferrites Mg0.96Pr0.04Fe2O4. The nanocomposites were subjected to characterization techniques like XRD (X-ray diffraction), SEM (scanning electron microscope) and VSM (vibrating sample magneto-meter). The XRD data confirmed the incorporation of praseodymium in spinel nano-ferrites. Non-homogeneous particle size distribution will be seen in SEM micrographs and core shell structure of prepared Nano-composites estimated. The hysteresis loop discloses the ferromagnetic nature of Nano-composites. The magnetic parameters like coercivity and saturation magnetization show variation with increase of ferrite additives. So, by controlling the amount of additives, one can acquire the desired properties. Two Nanocomposites FP1 = 25% and FP2 = 50% may be recommended for hyperthermia of cancer treatment.
机译:通过共沉淀途径合成尖晶石铁氧体Mg0.96pr0.04F2O4。采用原位聚合技术制备聚吡咯。在目前的工作中,通过混合聚吡咯聚合物和Mg-Pr-Ferrites Mg0.960R0.04Fe2O4来制造纳米复合材料。对纳米复合材料进行表征技术,如XRD(X射线衍射),SEM(扫描电子显微镜)和VSM(振动样品磁带)。 XRD数据证实了在尖晶石纳米铁氧体中的镨掺入。在估计的制备纳米复合材料的SEM显微照片和核心壳结构中将看到非均匀粒度分布。滞后环公开了纳米复合材料的铁磁性。胁迫和饱和磁化等磁性参数显示了铁氧体添加剂的增加。因此,通过控制添加剂的量,可以获得所需的性质。对于癌症治疗的热疗,可能推荐两个纳米复合材料FP1 = 25%和FP2 = 50%。

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