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Additive manufacturing of polyamide nanocomposites for electrostatic charge dissipation applications

机译:用于静电电荷耗散应用的聚酰胺纳米复合材料的添加剂制造

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摘要

Polyamide 6 (PA 6) nanocomposites are viable engineered nanocomposite materials with potential application in electrostatic discharge dissipation applications. Creating an electrically conductive path to dissipate electrostatic charges in such materials can be a viable solution to electrostatic discharge (ESD) concerns. The addition of nanofillers can also enhance mechanical properties of the parent polyamide 6, a structural thermoplastic ideal for 3D printing via fused deposition modelling (FDM). While improving the ESD capability, it is imperative to sustain the structural integrity of the nanocomposites. Hence, this study evaluated the mechanical, thermal, and electrical properties of 3D printed PA6 nanocomposites for electrostatic discharge applications. 3 and 5 wt% of carbon nanofibers (CNF) was compounded with PA6 using co-rotating twin screw extruder to produce 1.75 mm diameter monofilaments for fused deposition modelling (FDM). The test samples were printed using commercial-off-the-shelf (COTS) 3D printer, Lulzbot TAZ 6 FDM printer. Mechanical, electrical, and thermal characterization was carried out according to their respective ASTM standard. The tensile and flexural properties were enhanced by 3 wt% addition of CNF, but no significant improvement was observed at 5 wt%. The CNF nanocomposites exhibited good thermal stability and crystallization phenomenon at both loading levels. The volume resistivity of the of the PA6 matrix was reduced to order of 10~(11) and 10~(12) by 3 wt% and 5 wt% CNF addition respectively, which seems promising for manufacturing static discharge products.
机译:聚酰胺6(PA 6)纳米复合材料是可行的工程化纳米复合材料,具有潜在的应用在静电放电耗散应用中。在这种材料中产生以消散静电电荷的导电路径可以是静电放电(ESD)问题的可行解决方案。添加纳米填料还可以增强母体聚酰胺6的机械性能,通过熔融沉积建模(FDM)进行3D打印的结构热塑性塑料。在提高ESD能力的同时,必须维持纳米复合材料的结构完整性。因此,该研究评估了用于静电放电应用的3D印刷PA6纳米复合材料的机械,热和电性能。使用共旋转双螺杆挤出机将3和5wt%的碳纳米纤维(CNF)配混,以产生1.75mm直径的单丝,用于融合沉积建模(FDM)。使用商业现货(COTS)3D打印机,Lulzbot TAZ 6 FDM打印机打印测试样品。根据其各自的ASTM标准进行机械,电气和热表征。加入拉伸和弯曲性能3wt%CNF,但在5wt%中没有观察到显着改善。 CNF纳米复合材料在负载水平下表现出良好的热稳定性和结晶现象。 PA6基质的体积电阻率分别将10〜(11)和10〜(12)的顺序分别降低至10〜(11)和10〜(12)分别为5wt%的CNF加成,似乎有望制造静电放电产品。

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