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Electrochemical sensing platforms based on the different carbon derivative incorporated interface

机译:基于不同碳衍生物结合界面的电化学传感平台

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摘要

In this work we present a comparative study of carbon derivative applications in amperometric biosensors and their effects on the properties of these biosensors. Biosensors were prepared by Horseradish peroxidase (HRP) immobilization on the composite electrodes composed of carbon black, carbon nanofiber (CNF), extended graphite, multiwalled carbon nanotube (MWCNT), reduced graphene oxide (REGO) and poly(glycidyl methacrylate-co-vinylferrocene) (P(GMA-co-VFc)) as mediator, covalent linker, and host matrix for carbon derivatives. The modified pencil graphite electrode (PGE) was used for the detection of hydrogen peroxide and to follow electrochemical behavior of different carbon derivatives which were recorded. The electrochemical characterization was investigated by cyclic voltammetry and electrochemical impedance spectroscopy methods. Amperometric measurements showed that the REGO and MWCNT modified electrodes have excellent performance in comparison with other carbon derivatives studied.
机译:在这项工作中,我们将对碳衍生物在安培生物传感器中的应用及其对这些生物传感器性能的影响进行比较研究。通过将辣根过氧化物酶(HRP)固定在由炭黑,碳纳米纤维(CNF),扩展石墨,多壁碳纳米管(MWCNT),还原氧化石墨烯(REGO)和聚甲基丙烯酸缩水甘油酯-甲基丙烯酸二茂铁组成的复合电极上制备生物传感器)(P(GMA-co-VFc))作为碳衍生物的介体,共价接头和主体基质。改进的铅笔状石墨电极(PGE)用于检测过氧化氢,并遵循记录的不同碳衍生物的电化学行为。通过循环伏安法和电化学阻抗谱法研究了电化学表征。安培测量显示,与其他研究的碳衍生物相比,REGO和MWCNT修饰电极具有出色的性能。

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