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首页> 外文期刊>Materials science & engineering. C, Biomimetic and supramolecular systems >Fabrication of TiO_2 nanoparticles/surfactant polymer complex film on glassy carbon electrode and its application to sensing trace dopamine
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Fabrication of TiO_2 nanoparticles/surfactant polymer complex film on glassy carbon electrode and its application to sensing trace dopamine

机译:玻碳电极上TiO_2纳米粒子/表面活性剂聚合物复合膜的制备及其在痕量多巴胺检测中的应用

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摘要

A novel method for the fabrication of a TiO_2/Nafion nano-film on glassy carbon electrode (NTGCE) is described. In the presence of dispersant, TiO_2 nanoparticles were dispersed into water to give a homogeneous and stable suspension. After the solvent evaporation, a porous and uniform TiO_2 nano-film was obtained on the GCE surface. Further coated with Nafion, the complex film possesses remarkable stability in aqueous solution. This nano-film was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The prepared electrode showed excellent electrocatalytic behavior of dopamine and high concentration of ascorbic acid does not interfere with the dopamine detection. Based on this, an electrochemical method is developed for the determination of dopamine with simplicity and high sensitivity.
机译:描述了一种在玻璃碳电极(NTGCE)上制备TiO_2 / Nafion纳米膜的新方法。在分散剂的存在下,将TiO_2纳米颗粒分散到水中,得到均匀稳定的悬浮液。溶剂蒸发后,在GCE表面获得了均匀的多孔TiO_2纳米膜。进一步用Nafion涂覆,该复合膜在水溶液中具有显着的稳定性。该纳米膜通过扫描电子显微镜(SEM)和原子力显微镜(AFM)表征。制备的电极显示出优异的多巴胺电催化性能,高浓度的抗坏血酸不会干扰多巴胺的检测。基于此,开发了一种简便,灵敏的电化学方法测定多巴胺。

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