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Materials engineering for surface-confined flame retardancy

机译:表面受限阻燃材料工程

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摘要

Polymer materials flammability represents a major limitation to their use and hence to the development of most polymer-based advanced technologies. Environmental and safety concerns are leading to progressive phasing out of versatile and effective halogen-based fire retardants which, so far, ensured a satisfactory polymer fire hazard control. Among the intensive efforts which are being made to develop new, environmentally safe, polymer fire protection approaches, the recognition of the paramount role played by the polymer surface during combustion and the exploitation of the new nanotechnologies developed for polymer surface engineering offer a promising perspective for polymer fire retardance. Indeed, heat transfer to the polymer and diffusion to the gas phase of polymer degradation combustible volatiles, which both fuel the combustion, occur across the polymer surface which characteristics regulate the polymer combustion process. It is shown that by engineering the polymer material surface by intumescent coatings or layer by layer nano-deposition or by oxidic nanostructures sol-gel synthesis, polymer combustion can be conveniently slowed down to extinguishment, complying fire safety rules of specific applications, through the creation of a surface barrier to heat and mass transfer across the polymer surface.
机译:聚合物材料的易燃性代表了其使用的主要限制,因此也限制了大多数基于聚合物的先进技术的发展。出于环境和安全方面的考虑,逐步淘汰了通用且有效的卤素基阻燃剂,迄今为止,这些阻燃剂可确保令人满意的聚合物火灾隐患控制。在为开发新的,对环境安全的聚合物防火方法而付出的巨大努力中,对聚合物表面在燃烧过程中所发挥的最重要作用的认识以及对聚合物表面工程学开发的新纳米技术的开发提供了广阔的前景。聚合物阻燃性。实际上,传给聚合物的热量和扩散到聚合物降解的气相的扩散可燃挥发物,两者均助燃,在整个聚合物表面上发生,这调节了聚合物的燃烧过程。结果表明,通过膨胀性涂层或逐层纳米沉积或通过氧化纳米结构溶胶-凝胶合成对聚合物材料表面进行工程处理,可以通过创造满足特定应用的防火安全规则的聚合物燃烧,方便地减慢燃烧速度。表面屏障对聚合物表面传热和传质的影响。

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  • 来源
    《Materials Science & Engineering》 |2014年第10期|1-20|共20页
  • 作者单位

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

    Department of Applied Science and Technology and INSTM Local Unit, Politecnico di Torino, Alessandria Campus, Viale Teresa Michel 5,15121 Alessandria, Italy;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Fire retardants; Polymer combustion; Intumescent coatings; Layer by layer; Sol-gel processes; Cone calorimeter;

    机译:阻燃剂;聚合物燃烧;膨胀型涂料;逐层溶胶-凝胶法;锥形量热仪;

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