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Waste glass as binder in alkali activated slag-fly ash mortars

机译:废玻璃作为碱活化矿渣-粉煤灰砂浆中的粘合剂

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摘要

This paper illustrates the application of waste glass powder as part of the binder in slag-fly ash systems activated by NaOH and NaOH/Na2CO3 activators. To evaluate the reaction kinetics, reaction products, mechanical properties, and durability performance of glass powder modified alkali activated slag-fly ash systems, calorimetry test, X-ray diffraction, FTIR, strength test, drying shrinkage tests, and carbonation test were conducted. From the isothermal calorimeter results, glass powder shows a higher reactivity compared to fly ash but still lower than slag. The reaction products of glass power modified samples exhibit an enhancement of polymerization degree of Si-O-T, observed in FTIR. As a consequence, higher drying shrinkage exists in glass modified mortars. The mechanical performance of different samples is mostly controlled by the Ca/Si of dry mixtures and activator type. After the slag-fly ash binder system was modified by the waste glass, a significant enhancement of resistance to carbonation was identified, especially for NaOH/Na2CO3 activated mortars, which show an increase of 300% on the carbonation resistance ability compared to the reference sample. The Na/(Si + Al) ratio of dry mixtures exhibits a positive correlation with carbonation resistance.
机译:本文说明了玻璃废粉作为粘结剂在由NaOH和NaOH / Na2CO3活化剂活化的粉煤灰系统中的应用。为了评估玻璃粉改性的碱活化矿渣-粉煤灰系统的反应动力学,反应产物,机械性能和耐久性能,进行了量热测试,X射线衍射,FTIR,强度测试,干燥收缩率测试和碳化测试。从等温量热仪的结果来看,与粉煤灰相比,玻璃粉具有更高的反应性,但仍低于炉渣。在FTIR中观察到,玻璃粉改性样品的反应产物显示出Si-O-T的聚合度提高。结果,在玻璃改性的砂浆中存在较高的干燥收缩率。不同样品的机械性能主要由干燥混合物的Ca / Si和活化剂类型控制。用废玻璃改性炉渣-粉煤灰粘结剂系统后,发现抗碳化性显着提高,特别是对于NaOH / Na2CO3活化砂浆,与参考样品相比,抗碳化能力提高了300% 。干燥混合物的Na /(Si + Al)比与抗碳化性呈正相关。

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