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Structural evolution of hydrated cement compacts

机译:水合水泥压块的结构演变

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摘要

This paper provides a simplified and repeatable method for research on morphology and structure evolution of hydrated cement. Dry cement powders were compacted in a steel mould to absorb water for hydration. Cement compacts and hydrated compacts were characterized by capillary absorption, MIP, SEM-EDS or synchrotron small-angel X-ray scattering (SAXS). Results show water is fully saturated in the homogenous compacts. Followed by repeatable preparation of cement compacts, pore structure of hydrated cement compacts are also repeatedly. Hydration products are preferentially produced near cement particles due to difficulty of ions diffusion at later hydration of cement compact. Therefore, lager pore far from cement particles is less filled and smaller pore near cement particles is more filled. Simplified processing and structural evolution of hydrating cement will benefit to design and control of cement materials.
机译:本文为水化水泥的形态和结构演化研究提供了一种简化且可重复的方法。将干燥的水泥粉在钢模中压实,以吸收水分进行水合作用。通过毛细管吸收,MIP,SEM-EDS或同步加速器小角度X射线散射(SAXS)表征水泥压实和水合压实。结果表明,均质压块中的水已完全饱和。重复进行水泥压块的制备之后,水合水泥压块的孔结构也会反复出现。水合产物优选在水泥颗粒附近产生,这是由于在随后的水泥压块水合时离子扩散困难。因此,远离水泥颗粒的较大孔被较少填充,而靠近水泥颗粒的较小孔被较多填充。水化水泥的简化加工和结构演变将有利于水泥材料的设计和控制。

著录项

  • 来源
    《Materials and structures》 |2011年第10期|p.1735-1743|共9页
  • 作者

    Shen Yeqing; Deng Min; Lu Anqun;

  • 作者单位

    College of Materials Science and Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China ,College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu 241000, Anhui, China;

    College of Materials Science and Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China;

    College of Materials Science and Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    cement compact; capillary absorption; hydration; structural evolution;

    机译:水泥压块毛细吸收保湿结构演变;

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