Quinine steps back in time

Philip Ball

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Quinine steps back in time

机译：奎宁退后

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Chemists have long memories. The claim, dating back to 1918, that a crucial step in a synthesis of quinine had been carried out has been validated experimentally, closing a chapter in this fascinating story. "One of the greatest scientific achievements in a century" was how The New York Times hailed the 'total synthesis' of quinine reported in 1944 by Robert Woodward and William Doering at Harvard University1'2. But had they really achieved it at all? The debate has continued, sometimes with considerable heat, into the twenty-first century.

机译：化学家有很长的记忆。可以追溯到1918年的声称，已经完成了奎宁合成的关键步骤，这一说法已通过实验得到验证，从而结束了这个引人入胜的故事的一章。 “一个世纪以来最伟大的科学成就之一”是纽约时报如何赞扬哈佛大学的罗伯特·伍德沃德和威廉·杜林于1944年报道的奎宁的“全合成” 1'2。但是他们真的做到了吗？辩论一直持续到二十一世纪，有时甚至是相当激烈。

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《Nature》 |2008年第7182期|p.1065-1066|共2页
作者
Philip Ball;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类自然科学总论;
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Quinine steps back in time

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