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Relativistic effects in homogeneous gold catalysis

机译：均相金催化中的相对论效应

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摘要

Transition-metal catalysts containing gold present new opportunities for chemical synthesis, and it is therefore not surprising that these complexes are beginning to capture the attention of the chemical community. Cationic phosphine-gold(1) complexes are especially versatile and selective catalysts for a growing number of synthetic transformations. The reactivity of these species can be understood in the context of theoretical studies on gold; relativistic effects are especially helpful in rationalizing the reaction manifolds available to gold catalysts. This Review draws on experimental and computational data to present our current understanding of homogeneous gold catalysis, focusing on previously unexplored reactivity and its application to the development of new methodology.%含有金的过渡金属催化剂，尤其是cationic phosphine-gold(I)复合物， 正在成为种类越来越多的合成转化反应的强大催化剂。对金、尤其是 对相对论效应的理论研究，能为合理解释这些催化剂所观测到的活性 提供一个框架。David Gorin和F. Dean Toste利用实验和计算数据总结 了我们目前对均一的金催化作用的理解，重点是以前未研究过的活性 以及新方法的开发。
机译：Transition-metal catalysts containing gold present new opportunities for chemical synthesis, and it is therefore not surprising that these complexes are beginning to capture the attention of the chemical community. Cationic phosphine-gold(1) complexes are especially versatile and selective catalysts for a growing number of synthetic transformations. The reactivity of these species can be understood in the context of theoretical studies on gold; relativistic effects are especially helpful in rationalizing the reaction manifolds available to gold catalysts. This Review draws on experimental and computational data to present our current understanding of homogeneous gold catalysis, focusing on previously unexplored reactivity and its application to the development of new methodology.%含有金的过渡金属催化剂，尤其是cationic phosphine-gold(I)复合物， 正在成为种类越来越多的合成转化反应的强大催化剂。对金、尤其是 对相对论效应的理论研究，能为合理解释这些催化剂所观测到的活性 提供一个框架。David Gorin和F. Dean Toste利用实验和计算数据总结 了我们目前对均一的金催化作用的理解，重点是以前未研究过的活性 以及新方法的开发。

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  • 来源
    《Nature》 |2007年第7134期|p.395-403|共9页
  • 作者

    David J. Gorin; F. Dean Toste;

  • 作者单位

    Department of Chemistry, University of California at Berkeley, Berkeley, California 94720, USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 自然科学总论;
  • 关键词

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