Reversible nonpolar-to-polar solvent

首页> 外文期刊>Nature >Reversible nonpolar-to-polar solvent

【24h】

Reversible nonpolar-to-polar solvent

机译：可逆非极性至极性溶剂

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Imagine a smart solvent that can be switched rever sibly from a liquid with one set of properties to another that has very different proper -ties, upon command. Here we create such a system, in which a non-ionic liquid (an alcohol and an amine base) converts to an ionic liquid (a salt in liquid form) upon exposure to an atmosphere of carbon dioxide, and then reverts back to its non-ionic form when exposed to nitrogen or argon gas. Such switchable solvents should facilitate organic syntheses and separations by eliminating the need to remove and replace solvents after each reaction step.

机译：想象一下一种智能溶剂，可以根据命令将其从具有一组特性的液体可转换为另一种性质完全不同的液体。在这里，我们创建了一个这样的系统，其中非离子液体（一种醇和一种胺碱）在暴露于二氧化碳的气氛下会转化为离子液体（一种液体形式的盐），然后又恢复为非离子液体。暴露于氮气或氩气中呈离子形式。通过消除在每个反应步骤之后去除和替换溶剂的需要，这样的可转换溶剂应有助于有机合成和分离。

著录项

来源
《Nature》 |2005年第7054期|p.1102|共1页
作者

展开▼
作者单位

展开▼
收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类自然科学总论;
关键词

相似文献

外文文献
中文文献
专利

1. Unique reversibility in extraction mechanism of U compared to solvent extraction for sorption of U(Ⅵ) and Pu( Ⅳ) by a novel solvent impregnated resin containing trialkyl phosphine oxide functionalized ionic liquid [J] . Paramanik M., Panja S., Dhami P. S., Journal of Hazardous Materials . 2018,第jula15期

机译：与新型溶剂浸渍的含三烷基氧化膦功能化离子液体的树脂浸渍法相比，U萃取机理与溶剂萃取对U（Ⅵ）和Pu（Ⅳ）的吸附相比具有独特的可逆性
2. Dissociation of a Strong Acid in Neat Solvents: Diffusion Is Observed after Reversible Proton Ejection Inside the Solvent Shell [J] . Manoel Veiga-Gutierrez, Alfonso Brenlla, Carlos Carreira Blanco The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2013,第45期

机译：在纯溶剂中强酸的解离：在溶剂壳内部可逆质子喷射后观察到扩散
3. Processing of intractable polymers using reactive solvents. 6. A new reactive solvent concept based on reversible depolymerisation [J] . W.W.G.J. van Pelt, J.G.P. Goossens, H.E.H. Meijer, Polymer: The International Journal for the Science and Technology of Polymers . 2002,第21期

机译：使用反应性溶剂加工难处理的聚合物。 6.基于可逆解聚的新反应溶剂概念
4. Solvent induced reversible deformations of polymeric 3D microstructures for actuation and sensing applications [C] . Sima Rekstyte, Domas Paipulas, Mangirdas Malinauskas, Laser-based micro- and nanoprocessing XII . 2018

机译：溶剂诱导的聚合物3D微结构的可逆变形，用于驱动和传感应用
5. Structural Microheterogeneity in Ionic Liquid/Solvent Mixtures Influenced by Solvent Polarity and Ion Concentration [D] . Falola, Babatunde Olukunle. 2021

机译：离子液体/溶剂混合物中的结构微孔，受溶剂极性和离子浓度影响的溶剂混合物
6. Increase in activation rate of Pro-Tk-subtilisin by a single nonpolar-to-polar amino acid substitution at the hydrophobic core of the propeptide domain [O] . Kota Yuzaki, Yudai Sanda, Dong-Ju You, 2013

机译：在前肽域的疏水核心处通过单个非极性至极性氨基酸取代来增加Pro-Tk-枯草杆菌蛋白酶的激活率
7. Dissociation of a Strong Acid in Neat Solvents: Diffusion Is Observed after Reversible Proton Ejection Inside the Solvent Shell [O] . Manoel Veiga-Gutiérrez, Alfonso Brenlla, Carlos Carreira Blanco, 2013

机译：在整个溶剂中的强酸解离：在溶剂壳内的可逆质子喷射后观察到扩散
8. Reversible Tailoring of Mechanical Properties of Carbon Nanotube Forests by Immersing in Solvents. [R] . Abadi, P. P., Maschmann, M. R., Mortuza, S. M., 2014

机译：通过浸入溶剂中可逆地调整碳纳米管森林的力学性能。

Reversible nonpolar-to-polar solvent

摘要

著录项

相似文献

相关主题

期刊订阅