Interfaces and the driving force of hydrophobic assembly

Chandler D

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Interfaces and the driving force of hydrophobic assembly

机译：界面和疏水组件的驱动力

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摘要

The hydrophobic effect - the tendency for oil and water to segregate - is important in diverse phenomena, from the cleaning of laundry, to the creation of micro-emulsions to make new materials, to the assembly of proteins into functional complexes. This effect is multifaceted depending on whether hydrophobic molecules are individually hydrated or driven to assemble into larger structures. Despite the basic principles underlying the hydrophobic effect being qualitatively well understood, only recently have theoretical developments begun to explain and quantify many features of this ubiquitous phenomenon.

机译：疏水作用-油和水分离的趋势-在多种现象中很重要，从清洗衣物到创建新材料的微乳液，再到蛋白质组装成功能性复合物。该效果是多方面的，具体取决于疏水分子是单独水合还是被驱动组装成更大的结构。尽管定性地很好地理解了疏水作用的基本原理，但直到最近，理论发展才开始解释和量化这种普遍现象的许多特征。

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来源
《Nature》 |2005年第7059期|p. 640-647|共8页
作者
Chandler D;
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作者单位

Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类自然科学总论;
关键词
FREE-ENERGIES; LIQUID WATER; HYDRATION; SOLVATION; MODEL; SIMULATION; SOLUTES; CONVERGENCE; TEMPERATURE; TRANSITION;

机译：自由能;液态水;水合;溶剂化;模型;模拟;溶液;会聚;温度;过渡;

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专利

1. Hydrophobicity of counterions as a driving force in the self-assembly process: Dodecyltrimethylammonium chloride and parabens [J] . Ana Krofli?, Bojan ?arac, Janez Cerkovnik, Colloids and Surfaces, A. Physicochemical and Engineering Aspects . 2014,第Null期

机译：抗衡离子的疏水性作为自组装过程中的驱动力：十二烷基三甲基氯化铵和羟基苯甲酸甲酯
2. The Hydrophobic Effect as a Driving Force in the Self-Assembly of a [2 x 2] Copper(I) Grid [J] . Jonathan R.Nitschke, Marie Hutin, Gerald Bernardinelli Angewandte Chemie . 2004,第48期

机译：疏水效应作为[2 x 2] Copper（I）网格自组装中的驱动力
3. Born-Haber Cycle for Monolayer Self-Assembly at the Liquid-Solid Interface: Assessing the Enthalpic Driving Force [J] . Wentao Song, Natalia Martsinovich, Wolfgang M. Heckl, Journal of the American Chemical Society . 2013,第39期

机译：液-固界面上单层自组装的Born-Haber循环：评估焓驱动力
4. TMDSC in Distinguishing Between the Hydrophobic and Hydrophilic Forces Driving the Self Assembly of Lipid Nanotubes [C] . Janis Matisons, Thomas Barclay Annual Conference of the North American Thermal Analysis Society . 2014

机译：区分疏水性和亲水力驱动脂纳米管的自组装的疏水性和亲水性
5. Two studies on self-assembly of amphiphilic molecules: (1) 3-dimensional assembly of hydrophobically modified water soluble polymer (HMWSP); (2) 2-dimensional assembly of surfactants at the solid/water and air/water interfaces. [D] . Kumar, Vikram. 1997

机译：两性分子自组装的两项研究：（1）疏水改性水溶性聚合物（HMWSP）的3维组装；（2）表面活性剂在固体/水和空气/水界面的二维组装。
6. New evidence that the hydrophobic effect and dispersion are not major driving forces for nucleotide base stacking. [O] . S H Gellman, T S Haque, L F Newcomb 1996

机译：疏水作用和分散不是核苷酸碱基堆积的主要驱动力的新证据。
7. New evidence that the hydrophobic effect and dispersion are not major driving forces for nucleotide base stacking. [O] . Gellman, S H, Haque, T S, Newcomb, L F 1996

机译：疏水作用和分散不是核苷酸碱基堆积的主要驱动力的新证据。

Interfaces and the driving force of hydrophobic assembly

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