ACRYLIC THERMOSETS: A SAFE ALTERNATIVE TO FORMALDEHYDE RESINS

Guy Clamen; Richard Dobrowolski; Griffin Gappert; Barry Weinstein

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ACRYLIC THERMOSETS: A SAFE ALTERNATIVE TO FORMALDEHYDE RESINS

机译：丙烯酸酯类树脂：甲醛树脂的安全替代品

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Although prevalent in many industries, classical thermoset resins based on condensation of phenol, urea or melamine with formaldehyde have been under attack due to health and environmental issues. Of particular concern is exposure to and release of formaldehyde during processing. Latent formaldehyde in some finished products has also raised health concerns. This has attracted research into alternative chemistries which employ innocuous materials. Acrylic ther-mosets are a safe, attractive alternative to formaldehyde condensates. This chemistry produces bonded materials with excellent mechanical properties. The chemistry, mechanical properties and cure conditions of acrylic ther-mosets are discussed in this article.

机译：尽管在许多行业中很普遍，但基于酚，尿素或三聚氰胺与甲醛缩合的传统热固性树脂由于健康和环境问题而受到攻击。特别令人关注的是加工过程中甲醛的暴露和释放。一些成品中的潜在甲醛也引起了人们的健康担忧。这吸引了对采用无毒材料的替代化学的研究。丙烯酸热熔胶是甲醛缩合物的安全，有吸引力的替代品。这种化学作用产生具有优异机械性能的粘合材料。本文讨论了丙烯酸热熔马赛克的化学，机械性能和固化条件。

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来源
《Nonwovens World》 |2004年第2期|p.96-102|共7页
作者
Guy Clamen; Richard Dobrowolski; Griffin Gappert; Barry Weinstein;
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作者单位

Rohm & Hass France;

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正文语种 eng
中图分类纺织工业、染整工业;
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1. Bio-based thermoset alloys from epoxy acrylate, sesame oil- and castor oil-derived resins: Renewable alternatives to vinyl ester and unsaturated polyester resins [J] . Z Karami, MJ Zohuriaan-Mehr, K Kabiri, Polymers from Renewable Resources . 2019,第1a3期

机译：来自环氧丙烯酸酯的生物基热固性合金，芝麻油和蓖麻油衍生的树脂：可再生替代乙烯基酯和不饱和聚酯树脂
2. Hybrid thermosets from polyisocyanate/water glass/emulsifier systems: Effects of melamine-formaldehyde resin [J] . Castellà N., Grishchuk S., Karger-Kocsis J., Journal of Applied Polymer Science . 2011,第1期

机译：多异氰酸酯/水玻璃/乳化剂系统的混合热固性塑料：三聚氰胺-甲醛树脂的作用
3. Development of novel flame-retardant thermosets based on boron-modified phenol-formaldehyde resins [J] . Martin C, Ronda JC, Cadiz V Journal of Polymer Science, Part A. Polymer Chemistry . 2006,第11期

机译：基于硼改性酚醛树脂的新型阻燃热固性塑料的开发
4. New Eco-Friendly Thermoset Acrylic Resins Offer Clean Manufacturing, Reduced VOC Emissions, Excellent Performance [C] . Gero Nordman, Michael Kalbe, Bernd Reck Global Plastics Environmental Conference . 2010

机译：新型环保热固性丙烯酸树脂提供干净的制造，减少VOC排放，性能优异
5. Anaerobic treatment of petrochemical wastewater containing acrylic acid and formaldehyde [D] . Qu, Mingbo 1997

机译：含丙烯酸和甲醛的石化废水的厌氧处理
6. Bio-Based Alternatives to Phenol and Formaldehyde for the Production of Resins [O] . P. R. Sarika, Paul Nancarrow, Abdulrahman Khansaheb, 2020

机译：生物的苯酚和甲醛的替代品用于生产树脂
7. Novel halogen-free flame retardant thermoset from a hybrid hexakis (methoxymethyl) melamine/phosphorus-containing epoxy resin cured with phenol formaldehyde novolac [O] . 2009

机译：由苯酚甲醛酚醛清漆固化的混合六（甲氧基甲基）三聚氰胺/含磷环氧树脂的新型无卤阻燃热固性树脂
8. A Literature Review - Problem Definition Studies on Selected Toxic Chemicals. Volume 6. Occupational Health and Safety and Environmental Aspects of Urea-Formaldehyde Resins. [R] . Hsiao, S., Villaume, J. E. 1978

机译：文献综述 - 选择有毒化学品的问题定义研究。第6卷。尿素 - 甲醛树脂的职业健康和安全及环境方面。

ACRYLIC THERMOSETS: A SAFE ALTERNATIVE TO FORMALDEHYDE RESINS

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