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Photoactive UV-A transparent ZnO-Al_2O_3 coatings for singlet oxygen photogeneration

机译:光活性UV-A透明ZnO-AL_2O_3涂层的单线氧荧光

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摘要

We present the study of ZnO-Al_2O_3 thin coatings and nanocomposites prepared by a polymer-salt method. The coatings demonstrate high transparency in UV-A (wavelength is about 300 to 400 nm) and visible spectral ranges and the ability to generate singlet oxygen under UV irradiation. The materials were studied by spectroscopic methods, scanning electron microscopy, and x-ray diffraction analysis. Obtained ZnO-Al_2O_3 films are thin (about 250 to 300 nm) and fully cover the glass surface. They contain oriented ZnO nanocrystals 23 to 35 nm in size. Coatings chemical compositions strongly affect their structure and spectral properties. Al_2O_3 additions change the coatings' crystal structure by decreasing ZnO crystal size and making their spatial orientation more random and enhance the transparency in near UV due to significant increase of bandgap values.
机译:我们介绍了通过聚合物 - 盐法制备的ZnO-Al_2O_3薄涂层和纳米复合材料的研究。涂层在UV-A(波长为约300至400nm)和可见光谱范围内的高透明度和可见光谱范围以及在紫外线照射下产生单线氧的能力。通过光谱法,扫描电子显微镜和X射线衍射分析研究了材料。获得的ZnO-Al_2O_3薄膜薄(约250至300nm)并完全覆盖玻璃表面。它们含有定向ZnO纳米晶体23至35nm的尺寸。涂料化学组合物强烈影响其结构和光谱性能。 Al_2O_3通过减小ZnO晶体尺寸并使它们的空间方向更随机改变涂层的晶体结构,并通过显着增加的带隙值增加,增强近紫外线的透明度。

著录项

  • 来源
    《Optical engineering》 |2019年第7期|077105.1-077105.8|共8页
  • 作者单位

    ITMO University Photonics Department Saint-Petersburg Russian Federation;

    ITMO University Photonics Department Saint-Petersburg Russian Federation Saint-Petersburg State Technological Institute Saint-Petersburg Russian Federation The Bonch-Bruevich Saint-Petersburg State University of Telecommunications Saint-Petersburg Russian Federation;

    Saint-Petersburg Academic University of Russian Academy of Sciences Saint-Petersburg Russian Federation;

    Saint-Petersburg State Chemical-Pharmaceutical University Saint-Petersburg Russian Federation;

    ITMO University Photonics Department Saint-Petersburg Russian Federation The Bonch-Bruevich Saint-Petersburg State University of Telecommunications Saint-Petersburg Russian Federation;

    Saint-Petersburg State Electrotechnical University Saint-Petersburg Russian Federation;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    coating; spectra; light; singlet oxygen; oxide;

    机译:涂层;光谱;光;单线氧;氧化物;

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