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Recycling of surface-enhanced Raman substrates by ultraviolet cleaning

机译:通过紫外线清洁回收表面增强的拉曼底材

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摘要

Commercial substrates used for surface-enhanced Raman spectroscopy (SERS) are investigated for their reusability following cleaning with 254-nm UV light from a mercury lamp. SERS of Rhodamine 6G (Rh6G, a dye) and RDX (an explosive) is investigated. It is found that without UV irradiation, the substrate is usable only once, since it is not possible to dislodge the analyte either by prolonged immersion in distilled water or by ultrasonic cleaning. However, prolonged exposure to 254-nm UV followed by immersion in distilled water removes most of the analyte, making the substrate reusable for new SERS measurements. The technique of UV cleaning is demonstrated by recycling the same substrate several times and comparing SERS spectra taken after each cleaning cycle.
机译:研究了用于表面增强拉曼光谱(SERS)的商业基材在用汞灯的254 nm紫外线清洁后的可重复使用性。研究了若丹明6G(一种染料Rh6G)和一种RDX(一种炸药)的SERS。已经发现,在没有紫外线照射的情况下,基板只能使用一次,因为不可能通过长时间浸泡在蒸馏水中或通过超声波清洗来去除分析物。但是,长时间暴露在254 nm紫外线中,然后浸入蒸馏水中会去除大部分分析物,从而使基板可重复用于新的SERS测量。通过多次循环使用相同的基材并比较每个清洁周期后获得的SERS光谱,证明了UV清洁技术。

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