Polymeric electro-optic materials: optimization of electro-optic activity, minimization of optical loss, and fine-tuning of device performance

Larry R. Dalton

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Polymeric electro-optic materials: optimization of electro-optic activity, minimization of optical loss, and fine-tuning of device performance

机译：聚合电光材料：优化电光活性，最小化光损耗以及微调设备性能

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Translation of the large molecular hyperpolarizability of chro- mophores into large macroscopic electro-optic activity by electric field poling of chromophore-containing polymers is opposed by molecular- shape-dependent intermolecular electrostatic interactions. Modification of chromophore structure (shape) to minimize the deleterious effect of such interactions leads to significant improvement in electro-optic activ- ity. Drive voltage requirements for polymeric modulator devices are re- duced to values ranging from 0.7 to 5V.

机译：含色团聚合物的电场极化将发色团的大分子超极化性转变为大的宏观电光活性，这与分子形状相关的分子间静电相互作用相反。改变生色团结构（形状）以最大程度减少此类相互作用的有害影响，将导致电光活性的显着改善。聚合物调制器设备的驱动电压要求降低到0.7至5V的范围。

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《Optical engineering》 |2000年第2期|p.589-595|共7页
作者
Larry R. Dalton;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类光学仪器;
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1. Donor modification of nonlinear optical chromophores: Synthesis, characterization, and fine-tuning of chromophores' mobility and steric hindrance to achieve ultra large electro-optic coefficients in guest-host electro-optic materials [J] . Jieyun Wu, Chengcheng Peng, Hongyan Xiao Dyes and Pigments . 2014,第Null期

机译：非线性光学发色团的供体修饰：发色团的迁移率和位阻的合成，表征和微调，可在客体-主体电光材料中实现超大电光系数
2. Broadband electro-optic polymer modulators with high electro-optic activity and low poling induced optical loss [J] . H. Chen, B. Chen, D. Huang, Applied Physicsletters . 2008,第4期

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3. Microwave-assisted synthesis of novel julolidinyl-based nonlinear optical chromophores with enhanced electro-optic activityMicrowave-assisted synthesis of novel julolidinyl-based nonlinear optical chromophores with enhanced electro-optic activity [J] . Zhang Airui, Xiao Hongyan, Peng Chengcheng, RSC Advances . 2014,第110期

机译：微波辅助合成具有增强电光活性的新颖的基于黄体吡啶基的非线性光学发色团微波合成
4. Terahertz- Wave Generation Devices Using Electro-Optic Polymer Waveguides and Terahertz-Wave Low-Loss Cladding Materials [C] . Takahiro Kaji, Yukihiro Tominari, Toshiki Yamada, International Conference on Infrared, Millimeter, and Terahertz Waves . 2018

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5. High-performance thermo-optic switch and electro-optic modulator based on polymeric multi-mode waveguides with high device packing density for optical network applications. [D] . Lu, Xuejun. 2001

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8. High Performance Electro-Optic Polymeric Material Systems for Device Applications [R] . Jen, A. K. 2000

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Polymeric electro-optic materials: optimization of electro-optic activity, minimization of optical loss, and fine-tuning of device performance

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