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High quantum fluorescence yield of Er~(3+) at 1.5 μm in an Yb~(3+), Ce~(3+)-codoped CaF_2 crystal

机译:Yb〜(3 +),Ce〜(3+)掺杂CaF_2晶体中1.5μm处Er〜(3+)的高量子荧光产率

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摘要

For the first time, a quaternary doping system of Er~(3+), Yb~(3+), Ce~(3+), Na~+:CaF_2 single crystal was demonstrated to have high fluorescence yield in the eye-safe 1.5 μm region under 980 nm laser diode pumping, with relatively broad and flat gain curves. A simplified model was established to illustrate the effect of Ce~(3+) on the branching ratio for the Er~(3+) ~4I_(11/2) → ~4I_(13/2) transition. With 0.2-at.% Er~(3+) and 2.0-at.% Ce~(3+) in the quaternary-doped CaF_2 crystal, the branching ratio was estimated to be improved more than 40 times by the deactivating effect of Ce~(3+) on the Er~(3+) ~4I_(11/2) level. The quaternary-doped CaF_2 system shows great potential to achieve high laser performance in the 1.5 μm region.
机译:首次证明Er〜(3 +),Yb〜(3 +),Ce〜(3 +),Na〜+:CaF_2单晶的四元掺杂体系对人眼安全性高。在980 nm激光二极管泵浦下的1.5μm区域,具有相对宽且平坦的增益曲线。建立简化模型以说明Ce〜(3+)对Er〜(3+)〜4I_(11/2)→〜4I_(13/2)跃迁的支化比的影响。在四元掺杂的CaF_2晶体中,以0.2at。%的Er〜(3+)和2.0at。%的Ce〜(3+),通过Ce的去活化作用,估计其分支比提高了40倍以上。 Er〜(3+)〜4I_(11/2)电平上的〜(3+)。四元掺杂的CaF_2系统显示出在1.5μm范围内实现高激光性能的巨大潜力。

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