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首页> 外文期刊>Optical Materials >Investigation of up-conversion luminescent properties of Er~(3+)/Yb~(3+) co-doped ZrO_2-Al_2O_3 powders
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Investigation of up-conversion luminescent properties of Er~(3+)/Yb~(3+) co-doped ZrO_2-Al_2O_3 powders

机译:Er〜(3 +)/ Yb〜(3+)共掺杂ZrO_2-Al_2O_3粉末的上转换发光性能研究

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摘要

Er~(3+)/Yb~(3+) co-doped ZrO_2-Al_2O_3 powders are prepared by a solid-state reaction method. The up-conversion luminescence spectra excited by 980 nm shows three main emission bands. One red emission band is centered at 654 nm and two green ones are centered at 545 and 525 nm, corresponding to the transitions of ~4F_(9/2) → ~4I_(15/2), ~4S_(3/2) → ~4I_(15/2) and ~2H_(11/2) → ~4I_(15/2) of Er~(3+) ions, respectively. The dependence of up-conversion luminescent properties on dopant concentrations is investigated. It is found that higher sintering temperature could make aluminum dissolved in the zirconia lattice in term of the XRD patterns. This enhances the up-conversion efficiency.
机译:通过固相反应法制备了Er〜(3 +)/ Yb〜(3+)共掺杂的ZrO_2-Al_2O_3粉末。 980nm激发的上转换发光光谱显示出三个主要的发射带。一个红色发射带的中心位于654 nm,两个绿色发射带的中心位于545和525 nm,分别对应于〜4F_(9/2)→〜4I_(15/2),〜4S_(3/2)→的跃迁Er〜(3+)离子的〜4I_(15/2)和〜2H_(11/2)→〜4I_(15/2)。研究了上转换发光特性对掺杂剂浓度的依赖性。研究发现,较高的烧结温度会使铝溶解在氧化锆晶格中。这提高了上转换效率。

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