Electroreduction of methyl viologen in methanol and silicate thin films prepared by the sol-gel method

Krzysztof Maruszewski; Agnieszka Hreniak; Jan Czyzewski; Wieslaw Strek

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Electroreduction of methyl viologen in methanol and silicate thin films prepared by the sol-gel method

机译：溶胶-凝胶法制备的甲醇和硅酸盐薄膜中甲基紫精的电还原

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摘要

Bulk methanol solutions of methyl viologen (paraquat) can be reversibly reduced to its blue cation radical on transparent ITO electrodes. The intensity of the coloration is directly proportional to voltage applied to the cell. Such effect does not occur for aqueous paraquat solutions. Reversible blue coloration can also be obtained for a MV~(2+) -doped silicate thin film obtained by the sol-technique and sandwiched between two ITO plates.

机译：甲基紫精（百草枯）的本体甲醇溶液可以在透明ITO电极上可逆地还原为蓝色阳离子自由基。着色的强度与施加到电池的电压成正比。百草枯水溶液不会出现这种效果。对于通过溶胶技术获得并夹在两个ITO板之间的MV〜（2+）掺杂的硅酸盐薄膜，也可以获得可逆的蓝色着色。

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来源
《Optical Materials》 |2003年第3期|p.221-225|共5页
作者
Krzysztof Maruszewski; Agnieszka Hreniak; Jan Czyzewski; Wieslaw Strek;
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作者单位

Institute for Low Temperature and Structure Research Polish Academy of Sciences Okolna 2 50-950 Wroclaw Poland;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类工程材料学;
关键词
methyl viologen; electroreduction; sol-gel method; ITO electrodes;

机译：甲基紫精;电还原溶胶-凝胶法ITO电极;

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1. Spectroscopic and electrochromical properties of metallophthalocyanines in silicate bulks and thin films prepared by the sol-gel method [J] . Maruszewski K. Journal of Molecular Structure . 2000,第0期

机译：溶胶-凝胶法制备的硅酸盐块体和薄膜中金属酞菁的光谱和电致变色性质
2. Physicochemical properties of Ru(bpy)_3~(2+) entrapped in silicate bulks and fiber thin films prepared by the sol-gel method [J] . Krzysztof Maruszewski, Marek Jasiorski, Malgorzata Salamon, Chemical Physics Letters . 1999,第1a2期

机译：溶胶-凝胶法制备的Ru（bpy）_3〜（2+）包裹在硅酸盐块体和纤维薄膜中的理化性质
3. WATER PERMEATION PROPERTIES OF SIO2-RSIO(3/2) (R=METHYL, VINYL, PHENYL) THIN FILMS PREPARED BY THE SOL-GEL METHOD ON NYLON-6 SUBSTRATE [J] . Iwashita K., Minami T., Tadanaga K. Journal of Applied Polymer Science . 1996,第12期

机译：溶胶-凝胶法制备的SIO2-RSIO（3/2）（R =甲基，乙烯基，苯）薄膜在NYLON-6基质上的透水性能
4. Photocatalytic Activity of TiO2/Ti Film Prepared by Sol-gel Method on Methyl Orange Degradation [C] . Wenjie Zhang, Bo Yang, Jiawei Bai Advances in key engineering materials . 2011

机译：溶胶-凝胶法制备TiO2 / Ti薄膜对甲基橙降解的光催化活性
5. STUDIES ON THIRD-ORDER NONLINEAR OPTICAL PROPERTIES OF TRANSITION METAL OXIDE THIN FILMS PREPARED BY SOL-GEL METHOD [D] . Hashimoto, Tadanori 1995

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6. Structural and Luminescence Properties of Lu2O3:Eu3+ F127 Tri-Block Copolymer Modified Thin Films Prepared by Sol-Gel Method [O] . Angel de Jesus Morales Ramírez, Margarita García Hernández, Antonieta García Murillo, 2013

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7. Thin films-preparation, structure and properties. Photoelectrochemical properties of Sb-doped TiO2 film semiconductor electrode prepared by the sol-gel method. [O] . Toshinobu YOKO, Akira YUASA, Kanichi KAMIYA, 1987

机译：薄膜制备，结构和性质。通过溶胶 - 凝胶法制备的Sb掺杂TiO2膜半导体电极的光电化学性质。
8. Synthesis and Microstructure of Highly Oriented PbTiO3 Thin Films Prepared by a Sol-Gel Method [R] . Ryder, D. F., Chen, C., Spurgeon, W. A. 1989

机译：溶胶 - 凝胶法制备高取向pbTiO3薄膜的合成与显微结构

Electroreduction of methyl viologen in methanol and silicate thin films prepared by the sol-gel method

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