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Visible up-conversion luminescence in Er~3+:BaRiO_3 nanocrystals

机译:Er〜3 +:BaRiO_3纳米晶体中的可见上转换发光

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摘要

Visible emissions at 548, 528 and 660 nm have been observed from the sol-gel derived nanocrystalline Er~3+: BaTiO_3 powders under infrared excitations at both 980 and 810 nm. Combined with the energy level structure of Er~3+ and the decay kinetics of the green emissions, the up-conversion mechanism has been analyzed and explained. The bright green emission at 548 nm has been attributed to the ground state-directed transition from 4~S_3/2, which is populated through excited state absorption (ESA) for 810 nm excitation, and through both ESA and energy transfer (ET) processes for 980 nm excitation.
机译:从溶胶-凝胶衍生的纳米晶Er〜3 +:BaTiO_3粉末在980和810 nm的红外激发下均观察到了548、528和660 nm处的可见发射。结合Er〜3 +的能级结构和绿色发射的衰减动力学,分析并解释了上转换机理。 548 nm处的亮绿色发射归因于从4〜S_3 / 2的基态定向跃迁,该跃迁是通过810 nm激发态的吸收(ESA)以及ESA和能量转移(ET)过程而形成的980 nm激发。

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