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Optical and thermal analysis of ZnO-CdO-TeO_2 glasses doped with Nd~3+

机译:Nd〜3 +掺杂的ZnO-CdO-TeO_2玻璃的光学和热分析

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摘要

It is presented the Nd doping of the gfassy ZnO-CdO-TeO_2 ternary system. The Nd-doped oxide glasses were prepared by conventional melt-quenching method using three different compositions from this system. X-rays diffraction (XRD) diagrams in these materials reveal that they are basically vitreous structure. Infrared (IR) spectra of the glasses showed the characteristic bands at 665,670, and 675 cm-1, which correspond to the trigonal structure of TeO_3. The presence of Nd3* was detected in the visible and infrared region of the spectra by optical absorption (OA) measurements of the band gap and by photolumines-cence (PL) experiments. Glasses showed light emission due to the transition: 4F_3/2→4I_9/2 Differential thermal analysis (DTA) of these glasses have shown that T_g temperatures are in the 465-485 ℃ and T_c in the 800-1000 ℃ ranges.
机译:提出了方型ZnO-CdO-TeO_2三元体系的Nd掺杂。通过常规的熔融淬火方法,使用来自该体系的三种不同的组成,制备了掺钕氧化物玻璃。这些材料的X射线衍射(XRD)图表明它们基本上是玻璃结构。眼镜的红外(IR)光谱显示出在665670和675 cm-1处的特征带,它们对应于TeO_3的三角结构。通过带隙的光吸收(OA)测量和光致发光(PL)实验,在光谱的可见和红外区域检测到了Nd3 *的存在。玻璃由于过渡而发光:4F_3 / 2→4I_9 / 2这些玻璃的差热分析(​​DTA)显示T_g温度在465-485℃,T_c温度在800-1000℃。

著录项

  • 来源
    《Optical Materials》 |2011年第6期|p.823-826|共4页
  • 作者单位

    Departamento de Investigation en Polimeros y Materiales de la Universidad de Sonora Hermosillo Sonora Mexico;

    Departamento de Investigation en Fisica de la Universidad de Sonora Edificio 31 Hermosillo Sonora Mexico;

    Benemerita Universidad Autonoma de Puebla. Posgrado en Optoelectronica. Facultad de Cienaas Fisko-Matematicas. Av. 14 San Claudia Col. San Manuel Puebla Mexico;

    Departamento de Ingenieria Quimica y Metalurgia Universidad de Sonora Rosales y Blvd. Luis Entinas s. Col. Centro 83000. Hermosillo Sonora Mexico;

    Facultad de Cienaas Quimkas Universidad Autonoma de Baja California Tijuana BC Mexico;

    Lab/Crupo Materiales Vitreos y Cerdmicos lnst. E. Torroja CC Construction CS1C Madrid Spain;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    photoluminescence; photoacoustic; neodymium; tellurite; glasses;

    机译:光致发光光声钕;亚碲酸盐眼镜;

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