Mechanism of energy transfer in Sr_2CeO_4:Eu~(3+) phosphor

Oleg Viagin; Andrey Masalov; Irina Ganina; Yuriy Malyukin

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Mechanism of energy transfer in Sr_2CeO_4:Eu~(3+) phosphor

机译：Sr_2CeO_4：Eu〜（3+）荧光粉中的能量转移机理

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摘要

Blue-white phosphor Sr_2CeO_4 belongs to a particular class of optical materials whose luminescence is governed by optical transitions associated with the electron charge transfer. The originality of its crystal-lographic structure, a chain-like sequence of luminescent centers, permits an effective transfer of the electronic excitation energy from the host to doped centers. Sr_2CeO_4, pure and doped with Eu~(3+)-ions of different concentrations, was synthesized by the Pechini citrate-gel method. The luminescence spectra and luminescence decay curves of Sr_2CeO_4 and Sr_2CeO_4:Eu~(3+) at 300 and 80 K were investigated. The performed experiments revealed the Forster nonradiative energy transfer under the energy migration condition from the crystal host to the doped europium ions.

机译：蓝白色磷光体Sr_2CeO_4属于一类特殊的光学材料，其发光受与电子电荷转移相关的光学跃迁控制。它的晶体学结构的独创性，即发光中心的链状序列，使电子激发能从主体有效转移到掺杂中心。采用柠檬酸Pechini凝胶法合成了纯Sr_2CeO_4，并掺杂了不同浓度的Eu〜（3+）离子。研究了Sr_2CeO_4和Sr_2CeO_4：Eu〜（3+）在300和80 K时的发光光谱和发光衰减曲线。进行的实验表明，在能量迁移条件下，从晶体主体到掺杂euro离子的Forster非辐射能量转移。

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来源
《Optical Materials》 |2009年第12期|1808-1810|共3页
作者
Oleg Viagin; Andrey Masalov; Irina Ganina; Yuriy Malyukin;
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作者单位

Institute for Scintillation Materials STC 'Institute for Single Crystals' National Academy of Sciences of Ukraine 60 Lenin Ave. 61001 Kharkiv Ukraine;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类
关键词
Sr_2CeO_4 phosphor; charge transfer luminescence; Eu(III); energy transfer; foerster mechanism;

机译：Sr_2CeO_4荧光粉;电荷转移发光;（（III）;能量转移;福斯特机制;

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机译：用于WLED的单相可调谐Sr_2CeO_4：Eu〜（3+）荧光粉中的新型能量转移机制
2. Photoluminescence mechanisms of color-tunable Sr_2CeO_4: Eu~(3+), Dy~(3+) phosphors based on experimental and first-principles investigation [J] . Jie Li, Xi Li, Shengliang Hu, Optical Materials . 2013,第12期

机译：基于实验原理和第一性原理研究Sr_2CeO_4：Eu〜（3+），Dy〜（3+）荧光粉的光致发光机理
3. Concentration Dependence of Multipolar Mechanisms Responsible for Sm~(3+) -+ Eu~(3+) Energy Transfer in (Ca_(0.97-3x/5.64)Sr_(o.o3))2.82(VO_4)_2:0.12Eu~(3+),xSm~(3+) Phosphors [J] . Han-Yu Lin, Sheng-Yuan Chu ECS Journal of Solid State Science and Technology . 2013,第7期

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4. Photoluminescence of Red-Emitting Phosphor Sr_2CeO_4: Eu~(3+), Sm~(3+) for Light-Emitting Diodes [C] . Haiyan Jiao, Cairang LiMao, Rangcuo Cai International Conference on Education, Management, Information and Mechanical Engineering . 2017

机译：红发磷光体SR_2CEO_4：EU〜（3+），SM〜（3+）的发光二极管的光致发光
5. Energy transfer and waveguide studies of europium(3+) and terbium(3+)-doped 2 silicon dioxide-titanium dioxide glass prepared via the sol-gel route. [D] . Mancuso, Carmela. 2002

机译：通过溶胶-凝胶法制备的掺（（3+）和ter（3+）的2二氧化硅-二氧化钛玻璃的能量传输和波导研究。
6. Tunable Luminescence in Sr2MgSi2O7:Tb3+ Eu3+Phosphors Based on Energy Transfer [O] . Minhong Li, Lili Wang, Weiguang Ran, 2017

机译：基于能量转移的Sr2MgSi2O7：Tb3 +Eu3 +荧光粉的可调发光
7. Luminescence and energy-transfer mechanisms in Eu^{3+} -doped GaN epitaxial films [O] . Higuchi Shinya, Ishizumi Atsushi, Sawahata Junji, 2010

机译：Eu ^ {3+}掺杂的GaN外延膜中的发光和能量转移机理
8. Laser Time-Resolved Spectroscopy: Investigations of Energy Transfer in Eu(3+) and Er(3+) Doped YVO4. [R] . Venikouas, G. E., Powell, R. C. 1977

机译：激光时间分辨光谱：Eu（3+）和Er（3+）掺杂YVO4中能量转移的研究。

Mechanism of energy transfer in Sr_2CeO_4:Eu~(3+) phosphor

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