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Biosynthesis and characterization of Ti/Ni bimetallic nanoparticles

机译:Ti / Ni双金属纳米粒子的生物合成与表征

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Small particles of Ti/Ni have been synthesized by a bioreduction method. The controlling parameter was the pH of the solution where they were grown in. HREM and high-angle annular dark field in the electron microscope have been used to characterize the morphology and structural properties of such small particles. Well controlled sizes in the range of 1-4 nanometers and with a structure based on an fcc-like geometry for the smallest clusters and with more complex arrays for larger clusters were obtained. In general it was demonstrated that the bimetal nanoparticles appear in a set of structures including the core-shell type, with Ni as the shell.
机译:Ti / Ni小颗粒已通过生物还原法合成。控制参数是溶液在其中生长的溶液的pH。电子显微镜中的HREM和高角度环形暗场已用于表征此类小颗粒的形态和结构特性。获得了良好控制的尺寸,范围在1-4纳米范围内,并且具有基于类似fcc的几何形状的结构,用于最小的簇,而对于更大的簇则具有更复杂的阵列。总的来说,证明了双金属纳米颗粒以包括核-壳型的一组结构出现,其中Ni为壳。

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