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Structural and optical studies of ZnAl2O4:x% Cu2+(0 < x <= 1.25) nanophosphors synthesized via citrate sol-gel route

机译:柠檬酸溶胶-凝胶法合成ZnAl2O4:x%Cu2 +(0

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摘要

Nanocrystalline ZnAl2O4:x% Cu2+(0 < x <= 1.25) phosphor powders were prepared via the citrate sol-gel technique. The pure-phase cubic structures in this systems were verified by the powder X-ray diffraction. Energy Dispersive x-ray Spectroscopy analysis confirmed the presence of the expected elements (Zn, Al, O and Cu). Scanning Electron Microscopy showed that the morphology of the phosphor was dependent on the concentration of Cu2+. High-Resolution Transmission Electron Microscopy confirmed that the Cu2+ concentration does not significantly influence the crystallites sizes of the phosphors. Ultraviolet-visible spectroscopy results showed that the Cu2+ concentration influenced the band gap of the host. Photoluminescence results showed that the emission intensity of the powder sample was dependent on the Cu2+ concentration. The emission from the host lattice was observed at 394 nm, while Cu2+ showed major emission at 405 and minor emission at 574 nm. The emission at 405 nm was due to the 3d(8)4s(1) -> 3d(9) transitions of Cu2+. The Commission on Illumination color coordinate evidently showed shifts from the bluewish to the greenish region with an increase in Cu2+ concentration. (C) 2016 Elsevier B.V. All rights reserved.
机译:纳米晶态ZnAl2O4:x%Cu2 +(0 3d(9)跃迁。照明委员会的颜色坐标显然表明,随着Cu2 +浓度的增加,从蓝色区域变为绿色区域。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Optical Materials》 |2017年第2期|26-32|共7页
  • 作者单位

    Sefako Makgatho Hlth Sci Univ Dept Phys POB 94 ZA-0204 Medunsa South Africa;

    Univ Free State Dept Phys Qwaqwa Campus Private Bag X13 ZA-9866 Phuthaditjhaba South Africa;

    Univ Witwatersrand Sch Phys Private Bag 3 ZA-2050 Johannesburg South Africa;

    Univ Free State Dept Phys POB 339 ZA-9300 Bloemfontein South Africa;

    Univ Zululand Dept Chem KwaDlangezwa Campus Private Bag X1001 ZA-3886 Kwa Zulu South Africa;

    Univ Zululand Richards Bay Campus Private Bag X1001 ZA-3886 Kwa Dlangezwa South Africa;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Sol-gel; ZnAl2O4; Cu2+-doped; Luminescence; CIE;

    机译:溶胶凝胶ZnAl2O4;掺杂Cu2 +发光;CIE;

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