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2 mu m emission properties and hydroxy groups quenching of Tm3+ in germanate-tellurite glass

机译:锗-碲玻璃中Tm3 +的2μm发射特性和羟基猝灭

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摘要

Tm3+ activated germanate-tellurite glasses with good thermal stability and anti-crystallization ability were prepared. Efficient 2 gm fluorescence was observed in the optimal concentration Tm3+ doped glass and the corresponding radiative properties were investigated. For Tm3+: F-3(4) -> H-3(6) transition, high spontaneous radiative transition probability (260.75 s(-1)) and large emission cross section (7.66 x 10(-21) cm(2)) were obtained from the prepared glass. According to Dexter's and Forster's theory, energy transfer microscopic parameters were computed to elucidate the observed 2 mu m emissions in detail. Besides, the effect of hydroxy groups quenching was also quantificationally investigated'based on simplified rate equations. Results demonstrate that the optimal concentration Tm3+ doped germanatetellurite glass possessing excellent spectroscopic properties might be an attractive candidate for 2 mu m laser or amplifier. (C) 2016 Elsevier B.V. All rights reserved.
机译:制备了具有良好热稳定性和抗结晶能力的Tm3 +活化的锗酸盐-碲玻璃。在最佳浓度的Tm3 +掺杂玻璃中观察到有效的2 gm荧光,并研究了相应的辐射性能。对于Tm3 +:F-3(4)-> H-3(6)跃迁,高自发辐射跃迁几率(260.75 s(-1))和大发射截面(7.66 x 10(-21)cm(2))从制备的玻璃获得。根据德克斯特(Dexter)和福斯特(Forster)的理论,计算了能量传递微观参数,以详细阐明观察到的2微米排放量。此外,还基于简化的速率方程对羟基猝灭的影响进行了定量研究。结果表明,具有出色光谱性能的最佳浓度的Tm3 +掺杂锗铝酸盐玻璃可能是2μm激光或放大器的诱人候选物。 (C)2016 Elsevier B.V.保留所有权利。

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