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Fluorescence quantum yield of Yb3+-doped tellurite glasses determined by thermal lens spectroscopy

机译:热透镜光谱法测定掺Yb3 +的碲酸盐玻璃的荧光量子产率

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In this work, the combination of three different thermal lens spectroscopic methodologies was used to better determine the fluorescence quantum yield and to observe the concentration quenching in Yb3+-doped binary tellurite glasses (in mol%, 80TeO(2) 20Li(2)O and 80TeO(2) - 20WO(3)). The samples were synthesized by the conventional melt-quenching method and then studied using optical spectroscopy and thermal lens spectroscopy (Us). These characterizations enabled investigation of the radiative and nonradiative processes involved in the ytterbium doped systems. High fluorescence quantum yield was obtained for low Yb3+ doping (>90%), and in both glasses the Yb3+ presented concentration quenching mainly caused by impurities, host-ion interaction and OH- vibrations. The observations suggested that there is a possibility of doping the glasses with higher Yb concentration (>1.6 x 1021 ions/cm(3)) with low reduction of the quantum yield. (C) 2016 Elsevier B.V. All rights reserved.
机译:在这项工作中,结合使用三种不同的热透镜光谱学方法,可以更好地确定荧光量子产率,并观察掺Yb3 +的二元碲酸盐玻璃(以mol%计,80TeO(2)20Li(2)O和80TeO(2)-20WO(3))。通过常规的熔融淬火方法合成样品,然后使用光学光谱学和热透镜光谱学(Us)进行研究。这些表征使得能够研究in掺杂系统中涉及的辐射和非辐射过程。对于低Yb3 +掺杂(> 90%)可获得高荧光量子产率,并且在两种玻璃中,Yb3 +均表现出浓度猝灭,主要是由杂质,主体离子相互作用和OH-振动引起的。观察结果表明,有可能以较高的Yb浓度(> 1.6 x 1021离子/ cm(3))掺杂玻璃,而量子产率却降低得很低。 (C)2016 Elsevier B.V.保留所有权利。

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