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首页> 外文期刊>Optical Materials >Red light emitting nano-PVP fibers that hybrid with Ag@SiO_2@Eu(tta)_3phen-NPs by electrostatic spinning method
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Red light emitting nano-PVP fibers that hybrid with Ag@SiO_2@Eu(tta)_3phen-NPs by electrostatic spinning method

机译:静电纺丝法与Ag @ SiO_2 @ Eu(tta)_3phen-NPs混合的红色发光纳米PVP纤维

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摘要

This work demonstrated red light emitting nano-PVP fibers that incorporated with novel three-layer nanostructure of Ag@Si-2@Eu(tta)(3)phen nanoparticles (Ag@SiO2@Eu(tta)(3)phen-NPs), and the hybrid nano-PVP fibers were fabricated via a remarkably simple electrostatic spinning method. For Ag@SiO2@Eu(tta)(3)phen-NPs, the thickness of SiO2 is optimized to obtain the maximum luminescent intensity, as results, the optimized thickness of SiO2 is 20 nm. And the corresponding luminescent intensity (612 nm) of the Ag@SiO2@Eu(tta)(3)phen-NPs is enhanced up to 10 times compared with the pure Eu(tta)(3)phen complex, which indicates that with 20 nm SiO2 thickness, the localized surface plasmon resonance (LSPR) effect of Ag@SiO2 exhibits highest performance for enhancing luminescence. Moreover, the luminescent PVP fibers emit bright red light under the fluorescence microscope, which definitely confirms that the microenvironment provided by PVP polymer is absolutely suitable for the fluorescent composites. (C) 2018 Elsevier B.V. All rights reserved.
机译:这项工作证明了红色发光的纳米PVP纤维与Ag @ Si-2 @ Eu(tta)(3)phen纳米颗粒(Ag @ SiO2 @ Eu(tta)(3)phen-NPs)的新型三层纳米结构结合在一起,并通过非常简单的静电纺丝方法制备了杂化纳米PVP纤维。对于Ag @ SiO2 @ Eu(tta)(3)phen-NPs,优化SiO2的厚度以获得最大的发光强度,结果,SiO2的优化厚度为20 nm。与纯Eu(tta)(3)phen配合物相比,Ag @ SiO2 @ Eu(tta)(3)phen-NPs的相应发光强度(612 nm)增强了10倍,这表明,在SiO2厚度为nm的情况下,Ag @ SiO2的局域表面等离子体激元共振(LSPR)效应具有增强发光的最高性能。此外,发光的PVP纤维在荧光显微镜下发出鲜红色的光,这无疑证实了PVP聚合物提供的微环境绝对适合于荧光复合材料。 (C)2018 Elsevier B.V.保留所有权利。

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