Spectroscopy and upconversion processes in YAlO_3:Ho~3+ crystals

M. Malinowski; R. Piramidowicz; Z. Frukacz

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Spectroscopy and upconversion processes in YAlO_3:Ho~3+ crystals

机译：YAlO_3：Ho〜3 +晶体的光谱学和上转换过程

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Emission from the high lying excited states, energy transfer, and upconversion processes are investigated in YAlO_3Ho~3-. Selectively excited emission spectra in the range from 300 to 800 nm starting from the 3~D_3, 3~G_5 5~F_3 5~S_2 and 5~F_5 multiplets were measured at l5 K. This, together with the detailed absorption and excitation measurements at l5 K allowed determination of the Stark energy levels of Ho~3-- ions in YAlO_3 up to UV energies. The 5~S_2 fluorescence decays were recorded as a function of temperature and Ho~3- concentration in order to investigate the process of quenching of fluorescence due to cross relaxation among two ions. Conversion of red and infrared laser radiation to green 5~S_2 and blue 5~F_3 emission is reported. Under pu1sed resonant excitation of the 5~F_5 or 5~I_5 levels the upconversion was found to be due to energy transfer process between two excited ions. The photon avalanche effect was observed under cw excitation around 585 nm.

机译：在YAlO_3Ho〜3-中研究了高激发态的发射，能量转移和上转换过程。从3〜D_3、3〜G_5 5〜F_3 5〜S_2和5〜F_5多重峰开始，在300至800 nm范围内的选择性激发发射光谱在15 K下测量。这与详细的吸收和激发测量15 K可以确定YAlO_3中直至紫外线能量的Ho〜3-离子的斯塔克能级。记录5〜S_2荧光衰减与温度和Ho〜3-浓度的关系，以研究由于两个离子之间的交叉弛豫导致的荧光猝灭过程。据报道，红色和红外激光辐射转换为绿色5〜S_2和蓝色5〜F_3发射。在5〜F_5或5〜I_5能级的共振激发下，发现上转换是由于两个激发离子之间的能量转移过程。在585nm附近的cw激发下观察到光子雪崩效应。

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来源
《Optical Materials》 |1999年第4期|p.409-423|共15页
作者
M. Malinowski; R. Piramidowicz; Z. Frukacz;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种 eng
中图分类工程材料学;
关键词
YAP:Ho~3+; Upconversion; Avalanche process; Visible emission;

机译：YAP：Ho〜3 +;上转换;雪崩过程;可见光发射;

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1. UPCONVERSION AVALANCHE PROCESSES IN Ho~(3+)-Yb~(3+):YLF CRYSTAL [J] . E. OSIAC, S. KUECK, I. SOKOLSKA, Romanian reports in physics . 2008,第4期

机译：Ho〜（3 +）-Yb〜（3 +）：YLF晶体的上转换雪崩过程
2. Impact of organic additives on synthesis and upconversion luminescence properties in Ln~(3+) , Yb~(3+) (Ln~(3+) =Er~(3+)/Tm~(3+)/Ho~(3+) ) doped CaSc_2O_4 nanocrystals via hydrothermal method [J] . Li Fen, Li Jing, Wang Yue, Optical Materials . 2019,第Octa期

机译：有机添加剂对Ln〜（3+），Yb〜（3+）（Ln〜（3+）= Er〜（3 +）/ Tm〜（3 +）/ Ho〜（3）合成及上转换发光性能的影响
3. Energy-transfer upconversion of rare earth Ions in Ionic crystals: Case of Tm~(3+)/Ho~(3+)-codoped OYF_4 crystals [J] . Taiju Tsuboi, Hideyuki Murayama Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2006,第0期

机译：离子晶体中稀土离子的能量转移上转换：以Tm〜（3 +）/ Ho〜（3+）掺杂的OYF_4晶体为例
4. Energy transfer upconversion in Er~(3+)-doped and Er~(3+), Ho~(3+) -codoped Cs_2NaGdCl_6 crystals [C] . Dianyuan Wang, Jianglong Luo, Jianqiang Liu, ICO20: Lasers and Laser Technologies . 2005

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5. Optical spectroscopy, crystal field analysis, upconversion and energy transfer studies of Er(3+) doped yttrium vanadate single crystals. [D] . Kabro, Pierre. 1997

机译：掺Er（3+）钒酸钇钇单晶的光谱，晶体场分析，上转换和能量转移研究。
6. Investigation on the structure and upconversion fluorescence of Yb3+/Ho3+ co-doped fluorapatite crystals for potential biomedical applications [O] . Xiyu Li, Jingxian Zhu, Zhentao Man, -1

机译：Yb3 + / Ho3 +共掺杂氟磷灰石晶体的结构和上转换荧光研究潜在的生物医学应用
7. Luminescence of $La^{3+}$ and $Sc^{3+}$ impurity centers in $YAlO_3$ single-crystalline films [O] . Zorenko, Yu., Gorbenko, V., Voznyak, T., 2008

机译：$ YAlO_3 $单晶膜中$ La ^ {3 +} $和$ Sc ^ {3 +} $杂质中心的发光
8. Photoacoustic Spectroscopy Investigation of Radiationless Relaxation Processes of Cr(3+) in Crystals. [R] . Peterson, R. G., Powell, R. C. 1977

机译：光声光谱法研究晶体中Cr（3+）的无辐射弛豫过程。

Spectroscopy and upconversion processes in YAlO_3:Ho~3+ crystals

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