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Field-assisted femtosecond pump/probe measurements on conjugated systems

机译:共轭系统上的现场飞秒泵/探针测量

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摘要

The exciton dissociation in presence of an electric field is investigated in light emitting diodes of ladder-type poly(para-phenylene). The experimental setup allows us to directly observe the dynamics of the dissociation process with femtosecond-time resolution. Charge carriers are generated by two separate mechanisms. For early times, we observe an intra-chain dissociation corresponding to breaking during spectral relaxation. For longer times, we observe a time independent dissociation mechanism due to on-chain dissociation.
机译:在阶梯型聚对苯撑的发光二极管中研究了在电场存在下的激子离解。实验设置使我们能够以飞秒时间分辨率直接观察解离过程的动力学。电荷载流子由两种独立的机制产生。对于早期,我们观察到链内解离,对应于光谱弛豫期间的断裂。对于更长的时间,由于链上解离,我们观察到了与时间无关的解离机制。

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