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Perovskite solar cells fabricated under ambient air at room temperature without any post-treatment

机译:钙钛矿太阳能电池在室温下在环境空气下制造,没有任何后处理

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摘要

Solution process is the widely used simple way to prepare perovskite films for solar cells. For films fabricated from precursors with conventional solvents (DMF, DMSO or GBL), stable intermediate phase is formed in the films after spin-coating. Thermal annealing or other processes are required to transform this intermediate phase into perovskite crystal. Herein, we prepared perovskite films by a single spin-coating process without any post-treatment (post-treatment free process (PTFP)) based on perovskite precursor using 2-methoxyethanol (2-ME) as solvent. For the film obtained from 2-ME solution, a completely transformed perovskite film could been obtained immediately after spin-coating in glove box or under ambient air at room temperature. By using PTFP method with 2-ME solution, power conversion efficiency of 12.95% in glove box and 12.77% under ambient air have been achieved for planar perovskite solar cells (ITO/PEDOT:PSS/perovskite/PC61BM/BCP/Ag) without any assistance processes at room temperature. This very simple fabrication process of PTFP for perovskite films can be easily adopted in roll-to-roll production in commercialization.
机译:解决方案过程是广泛使用的简单方法,用于制备太阳能电池的钙钛矿薄膜。对于由常规溶剂(DMF,DMSO或GBL)制成的前体制造的薄膜,旋涂后在薄膜中形成稳定的中间相。需要热退火或其他过程以将该中间相转化为钙钛矿晶体。在此,我们通过单一的旋转涂覆方法制备钙钛矿膜,而没有任何后处理(治疗后自由过程(PTFP)),基于使用2-甲氧基乙醇(2-ME)作为溶剂。对于从2-Me溶液获得的薄膜,在旋涂在手套箱或室温下在环境空气下可以立即获得完全转化的钙钛矿膜。通过使用2-ME解决方案的PTFP方法,对于Parovskite太阳能电池(ITO / PEDOT:PSS / PEROVSKITE / PC61BM / BCP / AG),Glove Box的电力转换效率为12.95%和12.77%的环境空气下的12.77%室温下的辅助过程。在商业化的卷 - 卷生产中,可以容易地采用这种非常简单的PTFP制造过程。

著录项

  • 来源
    《Organic Electronics》 |2020年第11期|105918.1-105918.7|共7页
  • 作者单位

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China School of Science Chongqing University of Technology Chongqing 400054 PR China;

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China;

    College of Physics and Electronics Engineering Chongqing Normal University Chongqing 401331 PR China;

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China;

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China;

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China;

    School of Physics and Electronic Science Zunyi Normal College Zunyi 563002 PR China;

    Key Laboratory of Luminescence and Real-Time Analytical Chemistry Ministry of Education College of Chemistry and Chemical Engineering Southwest University Chongqing 400715 PR China;

    School of Materials and Energy Institute for Clean Energy and Advanced Materials Southwest University Chongqing 400715 PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Perovskite solar cell; Post-treatment free; Room temperature; Ambient air;

    机译:Perovskite太阳能电池;自由后治疗;室内温度;环境空气;

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