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Efficiency enhancement in perovskite solar cell utilizing solution-processable phthalocyanine hole transport layer with thermal annealing

机译:利用可溶液加工的酞菁空穴传输层和热退火技术提高钙钛矿太阳能电池的效率

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摘要

we demonstrate efficiency enhancement in perovskite solar cells (PSCs) utilizing a free-dopant hole transporting material (HTM), non-peripherally substituted octapentyl phthalocyanine (C5PcH_2) with thermal annealing. Particularly, by using thermal annealing approach, the external quantum efficiency at around 480 nm increase from 78 to 84%. Hence, the fill factor and short-circuit current density are markedly improved from 0.35 ± 0.02 to 0.55 ± 0.05 and from 18 ± 1 to 18.8 ± 0.3 mA cm~(-2), respectively. Finally, the best device is achieved with power conversion efficiencies of 12.2% by annealing at 130 ℃ for 10 min. The photoluminescence and photo-induced charge carrier extraction in linearly increasing voltages measurements indicate that the charge carrier mobility in C5PcH_2 increases, and thereby the hole extraction and transportation from the perovskite layer to the Au anode as well the photovoltaic performance of PCS is improved by using thermal annealing processing.
机译:我们展示了利用自由掺杂的空穴传输材料(HTM),非外围取代的八戊基酞菁(C5PcH_2)和热退火技术提高钙钛矿型太阳能电池(PSC)的效率。特别是,通过使用热退火方法,在480 nm附近的外部量子效率从78%提高到84%。因此,填充系数和短路电流密度分别从0.35±0.02显着提高到0.55±0.05和从18±1显着提高到18.8±0.3 mA cm〜(-2)。最后,通过在130℃下退火10分钟,可以实现功率转换效率为12.2%的最佳器件。线性增加的电压测量中的光致发光和光诱导电荷载流子提取表明,C5PcH_2中的电荷载流子迁移率增加,从而通过使用来改善空穴从钙钛矿层到金阳极的提取和传输以及PCS的光伏性能热退火处理。

著录项

  • 来源
    《Organic Electronics》 |2017年第4期|156-161|共6页
  • 作者单位

    Division of Electrical, Electronic and Information Engineering, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan;

    Division of Electrical, Electronic and Information Engineering, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan;

    Corporate R&D Planning and Administration Division, KANEKA Corporation, Suita, Osaka 565-0871, Japan;

    Department of Materials & Life Sciences, Sophia University, Kioi-cho, Chiyoda-ku, Tokyo 102-8554, Japan;

    Division of Electrical, Electronic and Information Engineering, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Phthalocyanine; Perovskite solar cells; Thermal annealing; Small molecule; Hole transport material;

    机译:酞菁;钙钛矿太阳能电池;热退火;小分子;空穴传输材料;

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