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首页> 外文期刊>Organic Electronics >Performance enhancement of poly (vinylidene fluoride-co-hexafluoro propylene)/polyethylene oxide based nanocomposite polymer electrolyte with ZnO nanofiller for dye-sensitized solar cell
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Performance enhancement of poly (vinylidene fluoride-co-hexafluoro propylene)/polyethylene oxide based nanocomposite polymer electrolyte with ZnO nanofiller for dye-sensitized solar cell

机译:染料敏化太阳能电池用ZnO纳米填料增强聚偏二氟乙烯/六氟丙烯共聚物/聚环氧乙烷基纳米复合聚合物电解质的性能

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摘要

Nanocomposite polymer electrolytes (NCPEs) were prepared by blending poly (vinylidene fluoride-co-hexafluoro propylene) copolymer (PVdF-HFP) and polyethylene oxide (PEO) polymers and incorporation of ZnO inorganic nanofiller (PVdF-HFP:PEO:EC:PC:NaI:I_2:ZnO). The highest ionic conductivity value of 8.36 mS cm~(-1) was recorded when 3 wt.% of ZnO inorganic nanofiller was incorporated into the NCPE system. Temperature-dependant ionic conductivity behaviour of NCPEs was analysed and proven to follow the Arrhenius thermal activated model. Structural studies of NCPEs were carried out using X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy analysis. NCPEs were used to fabricate Dye-sensitized solar cells (DSSCs). Enhancements in the solar light to electricity conversion efficiency (η) of DSSCs were observed in the presence of ZnO inorganic nanofiller in the NCPE system and NCPE with 3 wt.% ZnO represented the highest η of 7.33% under full sun irradiation.
机译:纳米复合聚合物电解质(NCPEs)通过将聚偏二氟乙烯-共六氟丙烯共聚物(PVdF-HFP)和聚环氧乙烷(PEO)聚合物共混并掺入ZnO无机纳米填料(PVdF-HFP:PEO:EC:PC: NaI:I_2:ZnO)。当将3 wt。%的ZnO无机纳米填料掺入NCPE系统中时,记录的最高离子电导率值为8.36 mS cm〜(-1)。分析了NCPE随温度变化的离子电导率行为,并证明遵循Arrhenius热激活模型。 NCPE的结构研究是使用X射线衍射(XRD)和傅里叶变换红外(FTIR)光谱分析进行的。 NCPE用于制造染料敏化太阳能电池(DSSC)。在NCPE系统中存在ZnO无机纳米填料的情况下,观察到DSSCs的太阳光到电转换效率(η)的增强,在全日照下,含有3 wt%ZnO的NCPE的最高η为7.33%。

著录项

  • 来源
    《Organic Electronics》 |2017年第10期|292-299|共8页
  • 作者单位

    Center for Ionics University of Malaya, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia;

    Center for Ionics University of Malaya, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia;

    Center for Ionics University of Malaya, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia;

    Center for Ionics University of Malaya, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    DSSC; Nanocomposite polymer electrolyte; PVdF-HFP; PEO; Zinc oxide; Filler;

    机译:DSSC;纳米复合高分子电解质;PVdF-HFP;PEO;氧化锌填料;

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